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Preparation and properties of waterborne poly(urethane-urea) ionomers effect of the type of neutralizing agent

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Abstract

A series of waterborne poly(urethane-urea) anionomers were prepared from isophorone diisocyanate (IPDI), polycaprolactone diol (PCL), dimethylol propionic acid (DMPA), ethylene diamine (EDA), and triethylamine (TEA), NaOH, or Cu(COOCH3)2 as neutralizing agent. This study was performed to decide the effect of neutralizing agent type on the particle size, viscosity, hydrogen bonding index, adhesive strength, antistaticity, antibacterial and mechanical properties. The particle size of the dispersions decreased in the following order: TEA based samples (T-sample), NaOH based samples(N-sample), and Cu(COOCH3)2 based sample (C-sample). The viscosity of the dispersions increased in the order of C-sample, N-sample, and T-sample. Metal salt based film samples (N and C-sample) had much higher antistaticity than TEA based sample. By infrared spectroscopy, it was found that the hydrogen bonding index (or fraction) of samples decreased in the order of T-sample, N-sample, and C-sample. The adhesive strength and tensile modulus/strength decreased in the order of T-sample, N-sample, and C-sample. The C-sample had strong antibacterial halo, however, T- and N-samples did not.

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Authors and Affiliations

  1. Department of Textile Engineering, Pusan National University, 609-735, Pusan, Korea

    Jung-Eun Yang, Young-Hee Lee, Young-Seok Koo, Young-Jin Jung & Han-Do Kim

  2. Department of Footwear Engineering, Dongseo University, 617-716, Pusan, Korea

    Young-Seok Koo

  3. Department of Fiber Engineering, Miryang National University, 627-702, Miryang, Korea

    Young-Jin Jung

Authors
  1. Jung-Eun Yang
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  2. Young-Hee Lee
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  3. Young-Seok Koo
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  4. Young-Jin Jung
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  5. Han-Do Kim
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Correspondence to Han-Do Kim.

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Yang, JE., Lee, YH., Koo, YS. et al. Preparation and properties of waterborne poly(urethane-urea) ionomers effect of the type of neutralizing agent. Fibers Polym 3, 97–102 (2002). https://doi.org/10.1007/BF02892624

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  • DOI: https://doi.org/10.1007/BF02892624

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