Cited References
03Koe: G.A. Koenig,Z. Kristallogr., 38, 529 (1903); as quoted in [30Kat]. (Equi Diagram; Experimental)
03Ste: S. Stevanoic,Z. Kristallogr., 37, 246 (1903); as quoted in [30Kat]. (Crys Structure; Experimental)
Indicates key paper.05Fri: K. Friedrich, “Copper and Arsenic,”Metallurgie, 2, 477–495 (1905) in German. (Equi Diagram; Experimental; Indicates presence of a phase diagram.)
06Hio: A.H. Hiorns, “Effect of Certain Elements on the Structure and Properties of Copper,”J. Soc. Chem. Ind. (London), 25, 616–623 (1906). (Equi Diagram, Meta Phases; Experimental)
Indicates key paper.08Fri: K. Friedrich, “Newer Investigations of the Melting Diagram of the System Copper-Arsenic and the Electrical Resistivity of Arsenic-Containing Copper,”Metallurgie, 5, 529–535 (1908) in German. (Equi Diagram; Experimental; Indicates presence of a phase diagram.)
Indicates key paper.10Ben: G.D. Bengough and B.P. Hill, “The Properties and Constitution of Copper-Arsenic Alloys,”J. Inst. Met., 3, 34–71 (1910). (Equi Diagram; Experimental; Indicates presence of a phase diagram.
13Pus: N. Puschin and E. Dischler, “The Electrical Conductivity of Copper-Arsenic Alloys,”Z. Anorg. Chem., 80, 65–70 (1913) in German. (Equi Diagram; Experimental)
16Bor: L.H. Borgstrom, “Algodonite and Whitneyite,”Geol. For. Forh., 38, 95–100 (1916) in German; TR:J. Chem. Soc., 114(2), 169–170 (1918); abstract only. (Crys Structure; Experimental)
19Bor: L.H. Borgstrom, “Algodonite and Whitneyite,”Am. Mineral., 4, 91 (1919); abstract only. (Crys Structure; Experimental)
27Han: D. Hanson and C.B. Marryat, “Investigation of the Effects of Impurities on Copper. Part III—The Effect of Arsenicon Copper. Part IV.—The Effect of Arsenic Plus Oxygen on Copper,”J. Inst. Met., 37, 121–168 (1927). (Equi Diagram; Experimental)
29Mac1: F. Machatschki, “Roentgenographic Examination of Remelted Algodonite and Whitneyite. Supplement,”Cent. Mineral. Geol. A 371–373 (1929) in German. {cm(Crys Structure; Experimental)}
29Mac2: F. Machatschki, “Algodonite and Whitneyite,”Nachr. Jahresber. Mineral. Beil. Bd., 59, 137–158 (1929) in German. (Crys Structure; Experimental)
29Ram: L.S. Ramsdell, “An X-Ray Study of the Domeykite Group,”Am. Mineral., 14, 188–196 (1929). (Crys Structure; Experimental)
30Kat: N. Katoh, “X-Ray Investigations on Copper-Arsenic Alloys,”Bull. Chem. Soc. Jpn., 5, 275–282 (1930);Z. Kristallogr., 76, 228–234 (1930). (Equi Diagram, Crys Structure; Experimental)
30Mac: F. Machatschki, “Natural Domeykite and Artificial Domeykite,”Cent. Mineral. Geol. A, 19–36 (1930) in German. {cm(Crys Structure; Experimental)}
34Hum: W. Hume-Rothery and G.W. Mabbott, and K.M.C. Evans, “The Freezing Points, Melting Points, and Solid Solubility Limits of the Alloys of Silver and Copper with the Elements of the B Sub-Groups,”Philos. Trans. R. Soc. (London) A, 233, 1–97 (1934). (Equi Diagram; Experimental)
36Gre: G.U. Greene, “A Study of Drosses from Lead Blast Furnaces,”Trans. AIME, 121, 171–193 (1936). (Crys Structure; Experimental)
37Mer: J.C. Mertz and C.H. Mathewson, “The Solid Solubilities of the Elements of the Periodic Sub-Group Vbin Copper,”Trans. AIME, 124, 59–77 (1937). (Equi Diagram, Crys Structure; Experimental)
38Ste: B. Steenberg, “Crystal Structure of Cu3As and Cu3P,”Ark. Kemi., Min. Geol., 12A(26), 15 (1938) in German. (Crys Structure; Experimental)
39Owe: E.A. Owen and E.W. Roberts, “Factors Affecting the Limit of Solubility of Elements in Copper and Silver,”Philos. Mag., 27, 294–327 (1939). (Equi Diagram, Crys Stucture; Experimental)
40Owe: E.A. Owen and V.W. Rowlands, “Solubility of Certain Elements in Copper and in Silver,”J. Inst. Met., 66, 361–378 (1940). (Equi Diagram, Crys Structure; Experimental)
40Pea: M.A. Peacock and A.S. Dadson, “On Rammelsbergite and Parammelsbergite: Distinct Forms of Nickel Diarsenide,”Am. Mineral., 25(9), 561–577 (1940). (Crys Structure; Experimental)
49Hum: W. Hume-Rothery, discussion on the paper by [49Owe],J. Inst. Met., 76, 682 (1949–1950). (Equi Diagram; Review)
49Owe: E.A. Owen and D.P. Morris, “The Application of X-Ray Methods to the Determination of Phase Boundaries in Metallurgical Equilibrium Diagrams,”J. Inst. Met., 76, 145–168 (1949–1950). (Equi Diagram; Experimental)
50Bol: J. Bolfa, R. Pastant, and M. Roubalt, “Realization of the Synthesis of Copper Arsenides by Fritting,”Compt. Rend., 230, 103–104 (1950) in French. (Equi Diagram, Crys Structure; Experimental)
51Wei: R. Weil and R. Hocart, “Simultaneous Synthesis of Cubic and Hexagonal Domeykite from Liquid Mixtures at Ordinary (Atmospheric) Pressures,”Compt. Rend., 233, 880–882 (1951) in French. (Equi Diagram, Crys Structure; Experimental)
52Pad: K. Padera, “Revision of the Domeykite-Algodonite Group,”Acad. Tcheque Sci. Bull. Int. Classe Sci., Math., Nat., Med., 52, 53–68 (1952). (Crys Structure; Experimental)
Indicates key paper.57Hum: W. Hume-Rothery and J. Burns, “Liquid-Solid Equilibrium in Copper and Silver Alloys; with an Appendix on the Equilibrium Diagram of the System Copper-Arsenic,”Philos. Mag., 2, 1177–1196 (1957). (Equi Diagram; Experimental; Indicates presence of a phase diagram.)
57Sch: K. Schubert, H. Breimer, W. Burkhardt, E. Gunzel, R. Haufler, H.L. Lukas, H. Vetter, J. Wegst, and M. Wilkens, “Some Structural Results in Metallic Phases II,”Naturwis-senschaften, 44, 229–230 (1957) in German. (Equi Diagram, Crys Structure; Experimental)
58Joh: Z. Johan, “Koutekite: A New Mineral,”Nature, 181(4622), 1553–1554 (1958). (Meta Phases, Crys Structure; Experimental)
60Hey: R.D. Heyding and G.J.G. Despault, “The Copper/Arsenic System and the Copper Arsenide Minerals,”Can. J. Chem., 38, 2477–2481 (1960). (Equi Diagram, Crys Structure; Experimental)
60Joh: Z. Johan, “Koutekite-Cu3As, A New Mineral,”Chem. Erde, 20, 217–226 (1960); abstract only. (Crys Structure; Experimental)
61Joh: Z. Johan, “Paxite, Cu2As3, A New Coppr Arsenide from Cerny Dul in the Giant Mts. (Krkonose),”Acta Univ. Carolinae, Geol., 2, 77–86 (1961); TR:Am. Mineral., 47, 1484–1485 (1962); abstact only. (Crys Structure; Experimental)
62Ber: L.G. Berry and R.M. Thompson, “X-Ray Powder Data for Ore Minerals,”The Peacock Atlas, Geological Society of America, New York, 30 (1962). (Crys Structure; Compilation)
65Man: M. Mansmann, “On Compounds of the Anti-LaF3 Structure Type,”Z. Kristallogr., 122, 399–406 (1965) in German. (Crys Structure; Experimental)
65Wan: P.N. Wang, G.F. Nikol'skaya, N.P. Luzhnaya, I.V. Evfimovsky, and A.A. Babitsyna, “A Study of the Copper-Arsenic System in the Region of the Compound Cu3As,”Izv. Akad. Nauk SSSR, Neorg. Mater., 1(9), 1476–1483 (1965) in Russian. (Equi Diagram; Experimental)
66mae: R. Maes and R. de Strycker, “The Copper-Tin-Arsenic Constitution Diagram—Part I: Solidification Reactions,”Trans. Metall. Soc. AIME, 236, 1328–1336 (1966); “Part II: Reactions in the Solid State,”Trans. Metall. Soc. AIME, 236, 1336–1341 (1966). (Equi Diagram; Experimental)
68Juz: R. Juza and K.V. Benda, “The Structure of Cu5As2,”Z. Anorg. Allg. Chem., 357, 238–246 (1968) in German. (Equi Diagram, Meta Phases, Crys Structure; Experimental)
69Aza: T. Azakami and A. Yazawa, “Activities of Arsenic and Indium in Liquid Copper Base Binary Alloys,”J. Min. Metall. Inst. Jpn., 85, 97–102 (1969) in Japanese., (Thermo; Experimental)
69Ben: K.V. Benda and R. Juza, “On the Ternary Phases in the System Lithium-Copper-Arsenic,”Z. Anorg. Allg. Chem., 371, 172–192 (1969) in German. (Equi Diagram, Crys Structure; Experimental)
71Bod: J. Bode, J. Gerlach, and F. Pawleck, “Measurements of the Activities of Antimony, Arsenic, Lead, and Bismuth in Liquid Copper,”Erzmetall., 24, 480–485 (1971) in German. (Thermo; Experimental)
71Guk: O.Y. Gukov, Y.A. Ugai, V.R. Pshestanchik, E.P. Domashevskaya, and L.B. Sen'kina, “Copper Arsenide Cu3As and the Phase Diagram Cu3As−Cu3P,”Izv. Akad. Nauk SSSR, Neorg. Mater., 7(8), 1338–1340 (1971); TR:Inorg. Mater. (USSR), 7(8), 1192–1194 (1971). (Equi Diagram, Crys Structure; Experimental)
71Lie: W. Liebisch and K. Schubert, “The Structure of Copper-Arsenic Alloys,”J. Less-Common. Met., 23, 231–236 (1971) in German. (Equi Diagram, Crys Structure; Experimental)
Indicates key paper.72Nau: J. Naud and P. Priest, “Contribution to the Study of the Copper-Arsenic System,”Mater. Res. Bull., 7, 783–792 (1972) in French. (Equi Diagram, Meta Phases, Crys Structure; Experimental; Indicates presence of a phase diagram.)
Indicates key paper.72Uga: Y.A. Ugai, V.R. Pshestanchik, O.Y. Gukov, and V.Z. Anokhin, “Phase Diagram of the System Cu−As and Properties of Cu5As2,”Izv. Akad. Nauk SSSR, Neorg. Mater., 8(10), 1734–1737 (1972) in Russian; TR:Inorg. Mater. (USSR), 8(10), 1526–1528 (1972). (Equi Diagram; Experimental; Indicates presence of a phase diagram.)
76Aza: T. Azakami and A. Yazawa, “Activity Measurements of Liquid Copper Binary Alloys,”Can. Metall Quart., 15(2), 111–122 (1976). (Thermo; Experimental)
77Igl: J.E. Iglesias and W. Nowacki, “Refinement of the Crystal Structure of α Domeykite, Structure Related to the A15 type,”Z. Kristallogr., 145, 334–345 (1977). (Crys Structure; Experimental)
79Jon: D.G. Jones and D.H. Philipp, “Arsenic Activity in Copper at 1100°C,”Trans. Inst. Min. Metall. C., 88, 7–10 (1979). (Thermo; Experimental)
80Lyn: D.C. Lynch, “Activity of Arsenic in Copper,”Metall. Trans. B, 11, 623–629 (1980). (Thermo; Experimental)
80Mie: A.R. Miedema, P.F. de Chatel, and F.R. de Boer, “Cohesion in Alloys—Fundamentals of A Semi-Empirical Method,”Physica, 100B, 1–28 (1980). (Thermo; Theory)
81Hin: M. Hino and T. Azakami, “Activities of Molten Cu−As, Ag−As, Au−As Binary and Fe−Cu−As Ternary Alloys,”J. Min. Metall. Inst. Jpn., 97(1126), 1269–1273 (1981) in Japanese. (Thermo; Experimental)
82Ble: C. Blendl and K.J. Range, “Cu3As4—A Columnar Structure With Polycondensed Heteronuclear Formula-Unit,”Z. Kristallogr., 159, 17–18 (1982) in German. (Equi Diagram, Meta Phases, Crys Structure; Experimental)
83Dab: D.M. Dabbs and D.C. Lynch, “Reevaluation of the Activity of As in Molten Cu,”Metall. Trans., B, 14B, 502–504 (1983). (Thermo; Experimental)
83Heh: T. Hehenkamp, “Thermodynamic Behavior of Impurity Atoms in α-Range Alloys of the Noble Metals and Nickel,”Ber. Bunsenges. Phys. Chem., 87, 806–811 (1983). (Thermo; Experimental)
83Lud: D. Ludecke, C. Ludecke, and T. Hehenkamp, “Thermodynamic Activity from Quasiisopiestic Measurements in α-Ag−As and α-Cu−As,”Acta Metallogr., 31, 95–100 (1983). (Thermo; Experimental)
83Nie: A.K. Niessen, F.R. de Boer, R. Boom, P.F. de Chatel, W.C.M. Mattens, and A.R. Miedema, “Model Predictions for the Enthalpy of Formation of Transition Metal Alloys II,”Calphad, 7(1), 51–70 (1983). (Thermo; Theory)
85Hin1: M. Hino and T. Azakami, “Activity of As in Molten Cu−As, Cu−S−As, and Fe−S−As Systems,”J. Min. Metall. Inst. Jpn., 101(171), 543–548 (1985) in Japanese. (Thermo; Experimental)
85Hin2: M. Hino and T. Azakami, “Arsenic and Antimony Activities in Copper Mattes by Mass-Spectrometric Method,”Complex Sulfides, Proc. Symp, A.E. Zunkel, Ed., TMS-AIME, Warrendale, PA, 723–734 (1985). (Thermo; Experimental)
Author information
Authors and Affiliations
Additional information
This work was supported by the ASM INTERNATIONAL and the Department of Energy through the Joint Program on Critical Compilation of Physical and Chemical Data coordinated through the Office of Standard Reference Data (OSRD), National Bureau of Standards. Literature searched through 1986. Part of the bibliographic search was provided by ASM INTERNATIONAL. Professor Laughlin is the ASM/NBS Data Program Category Editor for binary copper alloys.
Rights and permissions
About this article
Cite this article
Subramanian, P.R., Laughlin, D.E. The As−Cu (Arsenic-Copper) system. Bulletin of Alloy Phase Diagrams 9, 605–618 (1988). https://doi.org/10.1007/BF02881964
Issue Date:
DOI: https://doi.org/10.1007/BF02881964