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New synthetic method for cycloalkanedione

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Abstract

Four kinds of cycloalkanedione were prepared from bis-benzimidazole methiodide salt and bis-Grignard reagent, the addition-hydrolysis reaction of bis-benzimidazole methiodide salt with bis-Grignard reagent is reported and a novel method for the preparation of various kinds of cycloalkanedione is provided.

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References

  1. Fonken, G. S., Herr, M. E., Murray, H. C. et al., Microbiological hydroxylation of mono-cyclic alcohols,J. Am. Chem. Soc., 1967, 89(3):672.

    Article  CAS  Google Scholar 

  2. Niles, E. T., Snyder, H. R., Bicyclic olefin fromcis, trans, trans-cyclododecatriene and sulfuric acid,J. Org. Chem., 1961, 26:330.

    Article  CAS  Google Scholar 

  3. Blomquist, A. T., Spencer, R. D., Many-membered carbon rings (1)—Cyclization of some bifunctional ketenes,J. Am. Chem. Soc., 1948, 70(1):30.

    Article  CAS  Google Scholar 

  4. Kulkowit, S., Mckervey, A., Synthesis of some medium- and large-ring cycloalk-Zene-l, 4-diones by intramolecular coupling of α, ω-bis-diazoketones,J. C. S. Chem. Comm., 1978:1069.

  5. Shi Zhen, Gu Huan, Novel synthetic method for ketones from substituted benzimidazolium salts and Grignard reagents,Science in China, Ser. B, 1996, 39(6):654.

    Google Scholar 

  6. Tremsin, S.N., Pharmacology of new bis-quaternary derivatives of benzimidazole,Farmakol Alkaloidv Ikh Proizvod, 1972, 162.

  7. The Chemistry Departments of Lanzhou University and Fudan University,Experiments in Organic Chemistry (in Chinese), Beijing: People’s Education Press, 1978, 214–218.

    Google Scholar 

  8. Cope, A. C., Keough, A. H., Peterson, P. E. et al., Solvolysis ofcis-cyclooctene oxide,J. Amer. Chem. Sac., 1957, 79:3900.

    Article  CAS  Google Scholar 

  9. Ohloff, G., Giersch, W., Conversion of vicinal diols into dicarbonyl compounds by manganese dioxide,Angew. Chm. Internat. Edit., 1973, 12:401.

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Northwest University, 710069, Xi’an, China

    Zhen Shi, Juli Jiang & Huan Gu

Authors
  1. Zhen Shi
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  2. Juli Jiang
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  3. Huan Gu
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Project supported by the Natural Science Foundation of Shaanxi Province

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Shi, Z., Jiang, J. & Gu, H. New synthetic method for cycloalkanedione. Sc. China Ser. B-Chem. 41, 255–258 (1998). https://doi.org/10.1007/BF02879704

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  • DOI: https://doi.org/10.1007/BF02879704

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