Skip to main content
SpringerLink
Log in

The Sc−Si (Scandium-Silicon) system

  • Sc−Si
  • Published:
Bulletin of Alloy Phase Diagrams

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Cited References

  • 58Mat: B.T. Matthias, E. Corenzwit, and W.H. Zachariasen, “Superconductivity and Ferromagnetism in Isomorphous Compounds,”Phys. Rev., 112, 89 (1958). (Equi Diagram, Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  • 62Arb: J. Arbuckle and E. Parthe, “The Crystal Structures of Sc5Si3, Sc5Ge3, La5Ge3, and Ce5Ge3,”Acta Crystallogr., 15, 1205–1207 (1962). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 63Gla: E.I. Gladyshevskii and E.I. Emes-Misenko, “Crystal Structures of Silicon-Rich Scandium and Yttrium Silicides,”Zh. Strukt. Khim., 4(6), 861–864 (1963) in Russian; TR:J. Struct. Chem., 4, 793–795 (1963). (Crys Structure; Experimental)

    Google Scholar 

  • 64Sch: O. Schob and E. Parthe, “Digermanides of Scandium and Yttrium,”Monatsh. Chem., 95, 1466–1472 (1964) in German. (Crys Structure; Experimental)

    Article  Google Scholar 

  • 65Dvol: L.A. Dvorina and T.S. Verkhoglyadova, “Production of Rare-Earth Silicides by Arc Melting,”Izv. Akad. Nauk SSSR, Met., (6), 62–68 (1965) in Russian; TR:Russ. Metall., (6), 38–44 (1965). (Equi Diagram, Crys Structure; Experimental)

    Google Scholar 

  • 65Dvo2: L.A., Dvorina, “Physico-Chemical Properties of Silicides of Rare-Earth Metals,”Izv. Akad. Nauk SSSR, Neorg. Mater., 1 (10), 1772–1777 (1965) in Russian; TR:Inorg. Mater., 1, 1604–1608 (1965). (Equi Diagram; Experimental)

    Google Scholar 

  • 65Dvo3: L.A. Dvorina, V.S. Protasov and E.I. Gladyshevskii, “Scandium Monosilicide and Its Crystal Structures,”Izv. Akad. Nauk SSSR, Neorg. Mater., 1 (5), 711–714 (1965) in Russian; TR:Inorg. Mater., 1, 652–654 (1965). (Crys Structure; Experimental)

    Google Scholar 

  • 65Sam: G.V. Samsonov, T.S. Verkhogluadov, and L.A. Dvorina, “Hardness of Silicides of Some Rare-Earth Metals,”Fiz. Met. Metalloved., 19, 939–941 (1965) in Russian; TR:Phys. Met. Metallogr., 19 (6), 129–131 (1965). (Equi Diagram; Experimental)

    Google Scholar 

  • 65Sch: O. Schob and E. Parthe, “AB Compounds with Sc, Y, and Rare-Earth Metals. I. Scandium and Titanium Compounds with CrB and CsCl Structure,”Acta Crystallogr., 19, 214–224 (1965). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 66Dvo: L.A. Dvorina, “Preparation of Silicides of the Rare-Earth Metals,”Poroshk. Metall., 42(6), 92–94 (1966) in Russian: TR:Sov. Powder Met. Metall. Cerma., (6), 507–509 (1966). (Equi Diagram; Experimental)

    Google Scholar 

  • 66Ver: T.S. Verkhoglyadova and L.A. Dvorina, “High-Temperature Oxidation of Certain Rare-Earth Silicides,”Zh. Fiz. Khim., 40, 2250–2255 (1960) in Russian; TR:Russ. J. Phys. Chem., 40, 1209–1212 (1966). (Equi Diagram; Experimental)

    Google Scholar 

  • 67Ram: A. Raman, “On the AlB2-Type Phases,”Z. Metallkd., 58, 179–184 (1967). (Crys Structure; Theory)

    Google Scholar 

  • 72Sch: F.A. Schmidt, O.D. McMasters, and O.N. Carlson, “The Yttrium-Germanium System,”J. Less-Common Met., 26 (1), 53–70 (1972). (Equi Diagram, Crys Structure; Experimental; Indicates presence of a phase diagram)

    Article  Google Scholar 

  • 74Laz: V.I. Lazorenko B.M. Rud, Yu.B. Paderno, and L.A. Dvorina, “Electrical Properties of Scandium Silicides,”Izv. Akad. Nauk SSSR, Neorg. Mater., 10(11), 2087–2088 (1974) in Russian; TR:Inorg. Mater., 10, 1790–1791 (1974). (Equi Diagram, Crys Structure; Experimental)

    Google Scholar 

  • 76Mie: A.R. Miedema, “On the Heat of Formation of Solid Alloys. II,”J. Less-Common Met., 46, 67–83 (1976). (Equi Diagram; Theory)

    Article  Google Scholar 

  • 77Bar: I. Barin, O. Knacke, and O. Kubaschewski,Thermochemical Properties of Inorganic Substances (Supplement), Springer-Verlag, New York (1977). (Thermo; Compilation)

    Google Scholar 

  • 77Gla: E.I. Gladyshevskii, B.Ya. Kotur, O.I. Bodak, and V.P. Skvorchuk, “Scandium-Iron-Silicon Systems,”Dop. Akad. Nauk Ukr. RSR A, Fiz.-Mat. Tekh., 8, 751–754 (1977) in Ukrainian. (Equi Diagram; Experimental)

    Google Scholar 

  • 77Kot: B.Ya. Kotur, O.I. Bodak, and E.I. Gladyshevskii, “Scandium-Cobolt-Silicon System,”Dop. Akad. Nauk. Ukr. RSR A, Fiz.-Mat. Tekh., 7, 664–666 (1977) in Ukrainian. (Equi Diagram; Experimental)

    Google Scholar 

  • 78Bea: B.J. Beaudry and K.A. Gschneidner, Jr.,Handbook on the Physics and Chemistry of Rare-Earth Metals, Vol. 1. K.A. Gschneidner, Jr. and L. Eyring, Ed., North Holland Publishing Co., Amsterdam, 215 (1978). (Crys Structure; Compilation)

    Google Scholar 

  • 79Bra: H.F. Braun, G. Burri, and L. Linderer, “Partial Phase Diagram of the System Sc−Rh−Si,”J. Less-Common Met., 68(1), 1–8 (1979). (Equi Diagram; Experimental)

    Article  Google Scholar 

  • 79Rud: B.M. Rud, V.P. Lonnik, V.D. Levandovskii, and V.I. Lazorenko, “Paramagnetic Susceptibility of Scandium Monosilicide,”Izv. Akad. Nauk SSSR, Neorg. Mater., 15(4), 711–712 (1979) in Russian; TR:Inorg. Mater., 15, 555–556 (1979). (Equi Diagram; Experimental)

    Google Scholar 

  • 80Syc: N.I. Sychev, P.V. Gel'd and G.I. Kalishevich, “Thermodynamic Characteristics of Scandium Silicide (Sc5Si3), Titanium Silicide (Ti5Si3), and Vanadium Silicide (V5Si3),”Zh. Fiz. Khim., 54, 224–225 (1980) in Russian; TR:Russ. J. Phys. Chem., 54(1), 125–126 (1980). (Crys Structure, Thermo; Experimental)

    Google Scholar 

  • 81Ere: V.N. Eremenko, I.M. Obushenko, Yu.I. Buyanov, and K.A. Meleshevich, “Phase Equilibrium Diagram for Scandium-Germanium System,”Dop. Akad. Nauk Ukr. RSR A, 4, 80–83 (1981) in Ukrainian. (Equi Diagram; Experimental; Indicates presence of a phase diagram)

    Google Scholar 

  • 81Nie: A.K. Niessen and F.R. DeBoer, “The Enthalpy of Formation of Solid Borides, Carbides, Nitrides, Silicides, and Phosphides of Transition and Noble Metals,”J. Less-Common Met., 82, 75–80 (1981). (Equi Diagram, Thermo; Theory)

    Article  Google Scholar 

  • 82Vla: V.I. Vlasov, V.N. Lozovskii, and A.I. Koleshichenko, “Temperature Dependence of the Distribution Coefficient of Scandium in Silicon,”Izv. Akad. Nauk SSSR, Neorg. Mater., 18(3), 518 (1982) in Russian. (Equi Diagram; Experimental)

    Google Scholar 

  • 84Sud: V.S. Sudavtsova, G.I. Batalin, and V.P. Kurach, “Enthalpies of Formation of Silicon-Scandium Alloys in the Liquid State,”Ukr. Khim. Zh. (Russ. Ed.), 50(4), 339–340 (1984) in Russian. (Equi Diagram, Thermo; Experimental)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Materials Science and Engineering, University of Florida, 32611, Gainesville, FL, USA

    A. B. Gokhale & G. J. Abbaschian

Authors
  1. A. B. Gokhale
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. J. Abbaschian
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

This program was supported by ASM, under grant No. FG 101-1. Thermodynamic calculations were made using the F*A*C*T computer program at the McGill University, Montréal, Québec. The evaluators wish to thank Dr. K.A. Gschneidner, Jr., Director, Rare-Earth Information Center, Iowa State University, Ames, IA, for his help in providing some of the literature sources and a computer program for the critical evaluation of crystallographic data. Literature searched through 1984. Professor Abbaschian is the ASM/NBS Data Program Category Editor for binary silicon alloys.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gokhale, A.B., Abbaschian, G.J. The Sc−Si (Scandium-Silicon) system. Bulletin of Alloy Phase Diagrams 7, 333–336 (1986). https://doi.org/10.1007/BF02873002

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02873002

Keywords

Search

Navigation