Abstract
The sorption behavior of benzothiophene on marine sediments treated by different procedures was studied. Linear sorption isotherns were found for sorption of benzothiophene by no treatment and NaOAC-HOAC treatment sediments. The sediment treated by NaOAC-HOAC exhibited obviously largeK p value for benzothiophene. The observedKoc value was basically consistent with the value predicted from the benzothiophene solubility in water. Nonlinear isotherms were observed for adsorption of benzothiophene on the sediments treated by H2O2 and could be described by the Freundlich equation.
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Andersson, J. T., Bobinger, S., 1992. Polycyclic aromatic sulfur heterocycles. II. Photochemical oxidation of benzothiophene in aqueous solution.Chemosphere 24(4): 383–389.
Bintein, S., Devillers, J., 1994. QSAR for organic chemical sorption by soils and sediments.Chemosphere. 28: 1171–1188.
Chiou, C. T., Peters, L. J., Freed, V. H., 1979. A physical concept of soil—water equilibriums for nonionic organic compounds.Science 206: 831–832.
Grathwohl, P., 1990. Influence of organic matter from soils and sediments from various origins on the sorption of some chlorinated aliphatic hydrocarbons: Implications onK oc correlations.Environ. Sci. Technol. 24: 1687–1693.
Hassett, J. J., Means, J. C., Banwart, W. L. et al., 1980. Sorption of dibenzothiophene by soils and sediments.J. Environ. Qual. 9: 184–186.
Iaacson, P. J., Frink, C. R., 1984. Nonreversible sorption of phenolic compounds by sediment fractions: The role of sediment organic matter.Environ. Sci. Technol. 18: 43–48.
Jin Xiangcan, 1992. Chemistry of Pollutants in Sediments. China Environmental Science Press, Beijing, 376 pp.
Karickhoff, S. W., Brown, D. S., Scott, T. A., 1979. Sorption of hydrophobic pollutants on natural sediments.Water Res. 13: 241–248.
Kile, D. E., Chiou, C. T., 1995. Partition of nonpolar organic pollutants from water to soil and sediment organic matters.Environ Sci. Technol. 29: 1401–1406.
Smith, J. H., Mabey, W. R., Bohonos, N. et al., 1978. Environmental Pathways of Selected Chemicals in Freshwater Systems: Part I and II. USEPA Report Nos.600/7-77-113: 600/7-78-074.
Tessier, A., Campbell, P. G. C., Bisson, M., 1979. Sequential extraction procedure for the speciation of particulate trace metals.Anal. Chem. 51: 844–850.
Voice, T., Weber, W. J. Jr. 1983. Sorption of hydrophobic compounds by sediments, soils and suspended solids. I. Theory and background.Water Res.17: 1433–1441.
Wamer, J. S., 1975. Determination of sulfur—containing petroleum components in marine samples.In: Preceedings of the 1975 Conference on Prevention and Control of Oil Pollution, American Petroleum Institute, Washington D. C. pp. 97–101.
Yang Guipeng, 1996. Studies on the Geochemistry of Dimethyl Sulfide and other Organic Sulfur Compounds in the South China Sea and East China Sea. Ph. D. thesis, Ocean University of Qingdao, Qingdao, pp. 208.
Yang Guipeng, Zhang Zhengbin, 1994. The stepwise exchange action and steric hindrance effect of organic phenols on clays in seawater.Chin. J. Oceanol. Limnol. 12: 61–70.
Yang Guipeng, Zhang Zhengbin, Zhang Jianwu et al., 1997. Analysis and distribution features of benzothiophene in sediments of Nansha Islands sea area.Chin. J. Oceanol. Limnol. 15(3): 198–203.
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Project supported by the National “Eighth-Five Year Plan” Special Project (No.85-927-04-03).
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Gui-peng, Y., Zheng-bin, Z., Xin-tong, L. et al. Sorption of benzothiophene on marine sediments. Chin. J. Ocean. Limnol. 15, 350–356 (1997). https://doi.org/10.1007/BF02850569
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DOI: https://doi.org/10.1007/BF02850569