Abstract
Relative integrated intensities of the bands of theD 1Π →X 1Σ+ system of SnO have been measured by the technique of heterochromatic photographic photometry. Using the Rydberg-Klein-Rees Franck-Condon factors andr-centroids, the variation of electronic transition momentR e with the internuclear separationr is found to beR e (r)=const. (0.564r−1) in the range of 1.865 A≤r≤2.041A. The relative band strengths are derived. Effective vibrational temperature of the source is found to be 2559 K.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Ahrens L H and Taylor S R 1961 Spectrochemical analysis 2nd ed (Massachusetts: Addison Wesley)
Brode W R 1958Chemical spectroscopy 2nd ed (New York: John Wiley)
Connelly F C 1933Proc. Phys. Soc. 45 780
Dean J A 1960Flame photometry (New York: McGraw Hill)
Dube P S and Rai D K 1971J. Phys. B4 579
Hebert G R and Tyte D C 1964Proc. Phys. Soc. 83 629
Huber K P and Herzberg G 1979Constants of diatomic molecules (New York: Van Nostrand Reinhold)
Jevons W 1938Proc. Phys. Soc. 50 910
Kaiser H 1941Spectro-Chim. Acta 2 1
Lagerqvist A, Nilsson N E L and Wigartz K 1959Arkiv. Fysik. 15 521
Macpherson M T and Barrow R F 1981Ann. Rep. Prog. Chem. C78 221
Mahanti P C 1931Z. Phys. 68 114
Mahanti P C and Sen Gupta A K 1938Z. Phys. 109 39
Nicholls R W 1956The airglow and Aurorae (Oxford: Pergamon Press)
Nicholls R W 1964Extrait der Ann. de Geophys. 20 114
Nicholls R W 1977Annu. Rev. Astron. Astrophys. 15 197
Ornstein L S and Brinkman H 1931Proc. R. Acad. Amsterdam 34 33
Patil D C and Korwar V M 1978Acta Phys. Acad. Scien. Hungarica 44 371
Pearse R W B and Gaydon A G 1976The identification of molecular spectra 4th ed (London: Chapman and Hall)
Pierce W C and Nachtrieb N H 1941Ind. Eng. Chem. Anal. Ed. 13 774
Prahllad U D, Murthy B N and Murthy N S 1982J. Quant. Spectrosc. Radiat. Transfer 28 71
Sawyer R A 1963Experimental spectroscopy 3rd ed (New York: Dover)
Suchard S N 1975Spectroscopy data 1 (New York: Plenum Press)
Tawde N R and Patankar V S 1943Proc. Phys. Soc. 55 396
Thorne A P 1974Spectrophysics (London: Chapman and Hall)
Turner R G and Nicholls R W 1954Can. J. Phys. 32 468 and 475
Zhdanova L V and Nazimova N A 1974Fizika 1 106
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Rajamanickam, N. Intensity distribution in the bands of theD 1Π →X 1Σ+ system of SnO. Pramana - J Phys 25, 179–186 (1985). https://doi.org/10.1007/BF02847657
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02847657
Keywords
- Integrated intensities
- electronic transition moment
- relative band strengths
- vibrational temperature
- SnO(D 1Π →X 1Σ+) band system