Abstract
Agitation of the electrolyte by gas sparging was studied as a means of intensifying the electrowinning of copper. Diffusion layer profiles at the cathode were quantitatively measured using a new technique based on the mass transfer controlled codeposition of a tracer metal ion. Smooth, good quality cathodes were produced in a prototype cell at current densities up to 30 A/dm2 (270 asf).
Similar content being viewed by others
References
P. T. Strub and E. J. Clugston: Paper presented at 101st Annual Meeting of AIME, San Francisco, 1972.
V. A. Ettel: Paper presented at 100th Annual Meeting of AIME, New York, 1971.
W. W. Harvey, M. R. Randlett, and K. I. Bangeriskis: Paper presented at 102nd Annual Meeting of AIME, Chicago, 1973.
N. Ibl, P. Javet, and F. Stahel:Electrochim. Acta, 1972, vol. 17, pp. 733–39.
A. R. Despic and K. I. Popov:Mod. Aspects Electrochem., 1972, vol. 7, pp. 199–313.
C. Wagner:J. Electrochem. Soc., 1957, vol. 104, pp. 129–31.
J. R. Lloyd, E. M. Sparrow, and E. R. G. Eckert:J. Electrochem. Soc., 1972, vol. 119, pp. 702–07.
N. Ibl, E. Adam, J. Venczel, and E. Schalch:Chem.-Ing.-Tech., 1971, vol. 43, pp. 202–13.
V. A. Ettel, B. V. Tilak, and A. S. Gendron:J. Electrochem. Soc., 1974, vol. 121, pp. 867–72.
V. G. Levich:Physico-Chemical Hydrodynamics, Prentice-Hall, Englewood Cliffs, N.J., 1962.
R. N. Adams:Electrochemistry at Solid Electrodes, Marcel Dekker, New York, 1969.
D. Landolt, R. H. Muller, and C. W. Tobias:J. Electrochem. Soc., 1969, vol. 116, pp. 1384–90.
P. Hannaert:Ind. Chim. Belge, 1967, vol. 32 pp. 223–28.
Author information
Authors and Affiliations
Additional information
B. V. TILAK, formerly also with the J. Roy Gordon Research Laboratory is now with the Hooker Research Center, Niagara Falls, N.Y. 14302. This paper is based on the presentation made at the 102nd Annual Meeting of AIME, Chicago, 1973.
Rights and permissions
About this article
Cite this article
Ettel, V.A., Gendron, A.S. & Tilak, B.V. Electrowinning copper at high current densities. Metall Trans B 6, 31–36 (1975). https://doi.org/10.1007/BF02825675
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02825675