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Determination of molecular constants of scandium triiodide monomer and dimer from electron diffraction data

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Abstract

The molecular intensity function of a ScI3+SC2I6 mixture is solved using gas-phase electron diffractometry and taking into account the theoretical values of l(Sc-I). The symmetry of geometrical configuration, the internuclear distances, and vibration frequencies of the scandium triiodide monomer and dimer are determined.

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Authors and Affiliations

  1. United Institute of High Temperatures, Russian Academy of Sciences, Russia

    Yu. S. Ezhov, S. A. Komarov & V. G. Sevast’yanov

Authors
  1. Yu. S. Ezhov
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  2. S. A. Komarov
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  3. V. G. Sevast’yanov
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Translated fromZhurnal Struktumoi Khimii, Vol. 38, No. 3, pp. 489–494, May–June, 1997.

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Ezhov, Y.S., Komarov, S.A. & Sevast’yanov, V.G. Determination of molecular constants of scandium triiodide monomer and dimer from electron diffraction data. J Struct Chem 38, 403–407 (1997). https://doi.org/10.1007/BF02763605

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  • DOI: https://doi.org/10.1007/BF02763605

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