Skip to main content
SpringerLink
Log in

Fast ion conducting lithium glasses—Review

  • Glasses
  • Published:
Bulletin of Materials Science Aims and scope Submit manuscript

Abstract

For the last few years fast ion conducting lithium glasses are being studied due to their potential use in advanced electrochemical devices. A number of glass systems containing oxides, sulphides and other lithium compounds prepared by both conventional cooling and rapid quenching techniques have been reported. In this paper we review the transport properties of lithium ion conducting glasses. The special features of the ionic conduction process have been highlighted and some experimental techniques to study transport properties have been described. Some of the common observations of the properties have been discussed and finally some important problems for future development have been pointed out.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Abou El Anour A 1979 Ph.D. Thesis, Besancon

  • Abour El teil M, Heasley J and Omer M H 1978Phys. Chem. Glasses 19 37

    Google Scholar 

  • Angell C A 1981Solid State Ionics 5 659

    Article  CAS  Google Scholar 

  • Armstrong R D, Dickinson T and Wills P M 1974J. Electroanal. Chem. 53 389

    CAS  Google Scholar 

  • Barsoum M, Velez M H, Tuller H L and Uhlmann D R 1981Surfaces and interfaces in ceramic and ceramicmetal systems (eds) J Pask and A Evans (New York: Plenum) p. 567

    Google Scholar 

  • Basu B, Maiti H S and Paul A 1983Bull. Mater. Sci. 5 21

    CAS  Google Scholar 

  • Bauck F G K 1975Mass transport phenomena in ceramics (eds) A R Cooper and A H Heuer (New York: Plenum) p. 337

    Google Scholar 

  • Baurale J E 1969J. Phys. Chem. Solids 30 2657

    Article  Google Scholar 

  • Biefeld R M, Johnson R T and Banghman R J 1978J. Electrochem. Soc. 125 179

    Article  CAS  Google Scholar 

  • Boehm L and Angell C A 1979Fast ion transport in solids (eds) P Vashishtha, G K Shenoy and J N Mundy (North-Holland: Elsevier) p. 721

    Google Scholar 

  • Bottelberghs P H 1978Solid electrolytes, general principles, characterization, materials applications (eds) P Hagenmuller and W vanGool (New York: Academic Press) p. 145

    Google Scholar 

  • Bray P J and O’Keefe J G 1963Phys. Chem. Glasses 4 37

    Google Scholar 

  • Bray P J, Feller S A, Jellinson G E Jr and Yen Y H 1980J. Non Cryst. Solids 38, 39 93

    Article  Google Scholar 

  • Britzs D 1980Anal. Chem. 52 1166

    Article  Google Scholar 

  • Button D P, Tondon R P and Uhlmann D R 1980J. Non Cryst. Solids 42 297

    Article  CAS  Google Scholar 

  • Button D P, Tondon R P, King C, Velez M H, Tuller H L and Uhlmann D R 1982J. Non Cryst. Solids 49 129

    Article  CAS  Google Scholar 

  • Charles R J 1961J. Appl. Phys. 32 1115

    Article  CAS  Google Scholar 

  • Charles R J 1966J. Am. Ceram. Soc. 49 55

    Article  CAS  Google Scholar 

  • Doreau M, Anou El Anour A and Robert G 1980aMat. Res. Bull. 15 285

    Article  CAS  Google Scholar 

  • Doreau M and Robert G 1980Mater. Res. Bull. 15 1499

    Article  CAS  Google Scholar 

  • Downing H L, Peterson N L and Jain H 1982J. Non Cryst. Solids 50 203

    Article  CAS  Google Scholar 

  • Evastrop’eV K K, Veksler G I and Kondrat’eva B S 1974Dokl. Akad. Nauk. SSR 215 902

    Google Scholar 

  • Geissberger A E, Bucholty F and Bray P J 1982aJ. Non Cryst. Solids 49 117

    Article  CAS  Google Scholar 

  • Glass A M, Nassau K and Negram T J 1978J. Appl. Phys. 49 4808

    Article  CAS  Google Scholar 

  • Glass A M, Nassau K and Olson D H 1979Fast ion transport in solids (eds) P Vashishtha, G K Shenoy and J N Mundy (North Holland: Elsevier) p. 707

    Google Scholar 

  • Glass A M and Nassau K 1980J. Appl. Phys. 51 3756

    Article  CAS  Google Scholar 

  • Grant R J, Ingram M D and West A R 1977J. Electroanal. Chem. 80 239

    Article  CAS  Google Scholar 

  • Hagenmuller P, Levasseur A, Lucat C, Reau J M and Villeneuve G 1979Fast ion transport in solids (eds) P Vashishtha, G K Shenoy and J N Mundy (North-Holland: Elsevier) p. 637

    Google Scholar 

  • Hakim R M and Uhlmann D R 1971Phys. Chem. Glasses 12 132

    CAS  Google Scholar 

  • Hodge I M, Ingram M D and West A R 1976J. Electroanal. Chem. 74 125

    Article  CAS  Google Scholar 

  • Hughes K and Isard J O 1972Physics of electrolytes (ed.) J H Hladik (New York: Academic Press) Vol. 1 p. 351

    Google Scholar 

  • Irion M, Couzi M, Levasseur A, Reau J M and Brethous J C 1980Solid State Chem. 31 285

    Article  CAS  Google Scholar 

  • Jagla M and Isard J O 1980Mat. Res. Bull. 15 1327

    Article  CAS  Google Scholar 

  • Jeitschko W and Bither T A 1972aZ. Naturforsch. B27 1423

    Google Scholar 

  • Jeitschko W 1972bActa Crystallogr. B28 60

    Google Scholar 

  • Jeitschko W, Bither T A and Bierstedt 1977Acta Crystallogr. B33 2767

    CAS  Google Scholar 

  • Johnscher A K 1978J. Mater. Sci. 13 553

    Article  Google Scholar 

  • Johnson R T, Morrison B, Knotek M L and Biefeld R M 1975Phys. Lett. A54 403

    Google Scholar 

  • Johnson R T, Biefeld R M, Knotek M L and Morrison B 1976J. Electrochem. Soc. 123 680

    Article  CAS  Google Scholar 

  • Kone A, Barrau B, Souquet J L and Ribes M 1979Mat. Res. Bull. 14 393

    Article  CAS  Google Scholar 

  • Kone A, Ribes M and Souquet J L 1982Phys. Chem. Glasses 23 18

    CAS  Google Scholar 

  • Kulkarni A R, Maiti H S and Paul A 1981Glass formation and electrical conductivity in the system LiF-Li 2 O-Al(PO 3)3, paper presented in the 45th Annual Session of Indian Ceramic Society

  • Kulkarni A R, Maiti H S and Paul A 1984 (to be published)

  • Kulkarni A R 1984aLithium ion conducting glassy solid electrolytes in the LiF-Li 2 O-Al(PO3)3 system. Ph.D. Thesis submitted to IIT Kharagpur

  • Levasseur A, Cales B, Reau J M and Hagenmuller P 1978Mat. Res. Bull. 13 205

    Article  CAS  Google Scholar 

  • Levasseur A, Brethous J C, Reau J M and Hagenmuller P 1979Mater. Res. Bull. 14 921

    Article  CAS  Google Scholar 

  • Levasseur A, Kabla M, Brethous J C, Reau J M, Hagenmuller P and Couzi M 1979aSolid State Commun.32 839

    Article  CAS  Google Scholar 

  • Levasseur A, Brethous J C, Hagenmuller P, Berge R and Vignand G 1979bSolid State Commun.32 115

    Article  CAS  Google Scholar 

  • Levasseur A, Brethous J C, Reau J M, Hagenmuller P and Couzi M 1980Solid State Ionics 1 117

    Article  Google Scholar 

  • Levasseur A 1981Report EUR 7070FR Comm. European Communities Luxemberger p. 40

  • Levasseur A, Olazcuaga R, Kabla M, Zahir M, Hagenmuller P and Couzi M 1981Solid State Ionics 2 205

    Article  CAS  Google Scholar 

  • Levasseur A, Brethous J C, Kabla M and Hagenmuller P 1981bSolid State Ionics 5 651

    Article  CAS  Google Scholar 

  • MacDonald J R 1976aSuperionic conductors (eds) G D Mahan and W L Roth (New York: Plenum Press) p. 81

    Google Scholar 

  • MacDonald J R and Jacobs P W M 1976bJ. Phys. Chem. Solids 37 1117

    Article  CAS  Google Scholar 

  • Maiti H S, Kulkarni A R and Paul A 1983Lithium conducting glassy solid electrolytes in the LiF-Li 2 O-Al(PO3)3 system Paper presented in the 4th International Conference on Solid State Ionics Grenoble France

  • Malugani J P, Wasniewski A, Doreau M and Robert G 1978C R Acad. Sci. Paris 287 455

    CAS  Google Scholar 

  • Malugani J P and Robert G 1979Mater. Res. Bull. 14 1075

    Article  CAS  Google Scholar 

  • Malugani J P and Robert G 1980Solid State Ionics 1 519

    Article  CAS  Google Scholar 

  • Mercier R, Malugani J P, Fahys B and Robert G 1981Solid State Ionics 5 663

    Article  CAS  Google Scholar 

  • Nakajima T 19721971 annual report conference on electrical insulation and dielectric phenomena, Natl. Acad. Sci.

  • Nassau K, Wang C A and Grasso M 1979aAm. Ceram. Soc. 62 74

    Article  CAS  Google Scholar 

  • Nassau K, Wang C A and Grasso M 1979bAm. Ceram. Soc. 62 503

    Article  CAS  Google Scholar 

  • Nassau K, Glass A M and Olson D H 1980J. Electrochem. Soc. 127 2743

    Article  CAS  Google Scholar 

  • Nassau K, Cava R J and Glass A M 1981aSolid State Ionics 2 163

    Article  CAS  Google Scholar 

  • Nassau K and Glass A M 1981bJ. Non. Cryst. Solids 44 97

    Article  CAS  Google Scholar 

  • Otto K 1966Phys. Chem. Glasses 7 29

    CAS  Google Scholar 

  • Otto K and Milberg M E 1968J. Am. Ceram. Soc. 51 326

    Article  CAS  Google Scholar 

  • Peterson N L 1982Philos. Mag. 46 351

    Article  Google Scholar 

  • Prasad E, Sayer M and Vyas H M 1980J. Non Cryst. Solids 40 119

    Article  CAS  Google Scholar 

  • Pronkin A A 1978Sov. J. Phys. Chem. 4 388

    Google Scholar 

  • Ravaine D and Souquet J L 1973Proc. 24th Meeting ISE Eindhoven

  • Ravaine D and Souquet J L 1974J. Chim. Phys. 71 693

    CAS  Google Scholar 

  • Ravaine D and Souquet J L 1977Phys. Chem. Glasses 18 27

    CAS  Google Scholar 

  • Ravaine D and Souquet J L 1978Solid electrolytes, general principles, characterization, materials application (eds) P Hagenmuller and W vanGool (New York: Academic Press) p. 277

    Google Scholar 

  • Ribes M, Ravaine D, Souquet J L and Maurin M 1979Rev. Chim. Miner. 16 339

    CAS  Google Scholar 

  • Ribes M, Barrau B and Souquet J L 1980J. Non-Cryst. Solids 38, 39 271

    Article  Google Scholar 

  • Smedly S I and Angell C A 1978Solid State Commun. 27 21

    Article  Google Scholar 

  • Smedely S I and Angell C A 1980Mat. Res. Bull. 15 421

    Article  Google Scholar 

  • Shlesing M 1980Bull. Am. Phys. Soc. 25 434

    Google Scholar 

  • Souquet J L, Kone A and Ribes M 1980J. Non Cryst. Solids 38, 39 307

    Article  Google Scholar 

  • Stevels J M 1957The Electrical properties of glass in Handbook der Physics (Berlin: Springer-Verlag) Vol. 20 p. 380

    Google Scholar 

  • Tabby M P and Hendrickson J R 1980J. Non Cryst. Solids 38, 39 51

    Article  Google Scholar 

  • Takahashi T and Yamamoto Y 1979Chem. Lett. 135

  • Taylor H E 1959J. Soc. Glass Tech. 43 124T

  • Tomozawa M 1977Treattse on materials science and technology (eds) M Tomozawa and R H Doremus (New York: Academic Press) Vol 12 p. 283

    Google Scholar 

  • Tubandt C 1932Handbuch der Experimental Physik (eds) W Weiss and F Harms (Leipzig: Akademische Verlagsgesellschaft) Vol 21 p. 383

    Google Scholar 

  • Tuller H L, Button D P and Uhlmann D R 1980J. Non Cryst. Solids 40 93

    Article  CAS  Google Scholar 

  • Velez M H, Tuller H L and Uhlmann D R 1982J. Non Cryst. Solids 49 351

    Article  CAS  Google Scholar 

  • Wagner C 1956Z. Electrochem. 60 4

    CAS  Google Scholar 

  • Wagner C 1957International Committee of Electrochemical Thermodynamics and Kinetics, Proceeding 7th Meeting Butterworths London

  • Walraffen G E 1965J. Chem. Phys. 43 479

    Article  Google Scholar 

  • Warburg G 1884Ann. Phys. 21 622

    Article  Google Scholar 

  • Yakoto I 1955J. Phys. Soc. Jpn. 8 595

    Article  Google Scholar 

  • Yasui I, Ohta E, Hasegawa H and Imaoka M 1982J. Non Cryst. Solids 52 283

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Materials Science Centre, Indian Institute of Technology, 721 302, Kharagpur, India

    A R Kulkarni, H S Maiti & A Paul

Authors
  1. A R Kulkarni
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H S Maiti
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A Paul
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kulkarni, A.R., Maiti, H.S. & Paul, A. Fast ion conducting lithium glasses—Review. Bull. Mater. Sci. 6, 201–221 (1984). https://doi.org/10.1007/BF02743897

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02743897

Keywords

Search

Navigation