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Synthesis and crystal structure of sodiumtrans- nitrosoaquatetrachlororuthenate(II)

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Abstract

Synthesis of the compound NalRuNOCl4H2O] . 2H2O is reported. The complex was investigated by IR spectroscopy and X-ray phase and diffraction analyses. Crystal data: a = 7.0103(7), b = 11.133(1), c = 12.843(1) Å, β = 99.076(8)ℴ, V = 989.8(2) Å3, space group P2l/n, 2 = 4, dcalc = 2.348, dexp = 2.340 g/cm3. The structure consists of [ RUNOCI4H2O] complex onions, Na+ cations, and crystallization water molecules. The compound crystallizes as dark red concretions formed after prolonged storage of a saturated aqueous solution. The crystals are hygroscopic and spread when stored in air.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, USSR

    V. A. Emel'yanov, I. A. Baidina, S. A. Gromilov, A. V. Virovets & A. V. Belyaev

Authors
  1. V. A. Emel'yanov
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  2. I. A. Baidina
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  3. S. A. Gromilov
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  4. A. V. Virovets
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  5. A. V. Belyaev
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Translated fromZhurnal Strukturnoi Khimii, Vol. 41, No. 3, pp. 567-571, May–June, 2000.

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Emel'yanov, V.A., Baidina, I.A., Gromilov, S.A. et al. Synthesis and crystal structure of sodiumtrans- nitrosoaquatetrachlororuthenate(II). J Struct Chem 41, 463–467 (2000). https://doi.org/10.1007/BF02742006

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  • DOI: https://doi.org/10.1007/BF02742006

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