Skip to main content
SpringerLink
Log in

New lithium-ion conducting perovskite oxides related to (Li, La)TiO3

  • Published:
Journal of Chemical Sciences Aims and scope Submit manuscript

Abstract

We describe the synthesis and lithium-ion conductivity of new perovskite-related oxides of the formulas, LiCa1.65□0.35Ti1.3B1.7O9 (B =Nb,Ta)(I,II), LiSr2Ti2.5W0.5O9 (III) and LiSr1.65□0.35Ti2.15W0.85O9(IV). OxidesI andII crystallize in orthorhombic (GdFeO3-type) structure, while oxidesIII andIV possess cubic symmetry. All of them exhibit significant lithium-ion conduction at high temperatures, the highest conductivity of ∼ 10−2S/cm at 800°C among the oxides is exhibited by the composition IV. The results are discussed in the light of previous work on lithium-ion conducting perovskite oxides containingd 0 cations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Robertson A D, West A R and Ritchie A G1997Solid State Ionics 104 1

    Article  CAS  Google Scholar 

  2. Gopalakrishnan J, Shukla A K and Thangadurai V 1999Curr. Sci. 76 1473

    CAS  Google Scholar 

  3. Belous A G, Novitskaya G N, Polyanetskaya S V and Gornikov Yu I 1987Izv. Akad. Nauk SSSR, Neorg. Mater. 23 470

    CAS  Google Scholar 

  4. Fourquet J L, Duroy H and Crosnier-Lopez M P 1996J. Solid State Chem. 127 283

    Article  CAS  Google Scholar 

  5. Alonso J A, Sanz J, Santamaría J, León C, Várez A and Fernández-Díaz M T 2000Angew. Chem., Int. Ed. Engl. 39 619

    Article  CAS  Google Scholar 

  6. Thangadurai V, Shukla A K and Gopalakrishnan J 1999Chem. Mater. 11 835

    Article  CAS  Google Scholar 

  7. Inaguma Y, Liquan C, Itoh M, Nakamura T, Uchida T, Ikuta H and Wakihara M 1993Solid State Commun. 86 689

    Article  CAS  Google Scholar 

  8. Bhuvanesh N S P and Gopalakrishnan J 1997J. Mater. Chem. 7 2297

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Solid State and Structural Chemistry Unit, Indian Institute of Science, 560 012, Bangalore, India

    Litty Sebastian, A. K. Shukla & J. Gopalakrishnan

Authors
  1. Litty Sebastian
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. K. Shukla
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. Gopalakrishnan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to J. Gopalakrishnan.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sebastian, L., Shukla, A.K. & Gopalakrishnan, J. New lithium-ion conducting perovskite oxides related to (Li, La)TiO3 . J Chem Sci 113, 427–433 (2001). https://doi.org/10.1007/BF02708781

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02708781

Key words

Search

Navigation