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Characterization and catalytic properties of titanium silicalite-1 catalyst

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Abstract

Titanium silicalite 1 (TS-1) catalyst was prepared by three different hydrothermal synthesis methods. XRD, elemental analysis, SEM, IR,29Si MAS NMR, UV-vis DRS, physical adsorption of nitrogen, and EXAFS analysis were then performed to evaluate its physical properties. For a test of catalytic activity, liquid phase 2-butanol oxidation and 1-hexene epoxidation using hydrogen peroxide as an oxidant were conducted. The crystal size of the TS-1 catalyst was shown to have a considerable effect on the 1-hexene epoxidation, and smaller crystals resulted in higher activity.

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Authors and Affiliations

  1. Dept. of Chem. Eng., College of Eng., Inha Univ., 402-751, Inchon, Korea

    Yong Sig Ko & Wha Seung Ahn

  2. Dept. of Ind. Chem., Sinsung Junior College, 343-860, Dangjin-gun, Korea

    Yong Sig Ko

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  1. Yong Sig Ko
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  2. Wha Seung Ahn
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Correspondence to Wha Seung Ahn.

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Ko, Y.S., Ahn, W.S. Characterization and catalytic properties of titanium silicalite-1 catalyst. Korean J. Chem. Eng. 15, 182–191 (1998). https://doi.org/10.1007/BF02707071

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  • DOI: https://doi.org/10.1007/BF02707071

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