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Dehydrogenation of cyclohexanol to cyclohexanone over Cu/SiO2 catalysts : Dispersion and catalytic activity

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Abstract

Copper catalysts supported on silica (Cu/SiO2) were prepared by three different methods; incipient wetness, precipitation, and ion exchange. Catalytic properties in the dehydrogenation of cyclohexanol over these catalysts were examined. Copper surface area increased in the order of incipient wetness precipitation ion-exchange method for the catalysis with the same loading of copper. Conversion was mainly dependent on the copper surface area regardless of preparation methods, and selectivity to cyclohexanone was very high for all Cu/SiO2 catalysts.

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References

  • Chang, H.-F. and Saleque, M. A.,“Catalytic Activities of Electroless Plated Cu/alumina Catalysts for the Dehydrogenation of Cyclohexanol”,J. Mol CataL,88, 223 (1994).

    Article  CAS  Google Scholar 

  • Chang, H.-F. and Saleque, M. A.,“Dependence of Selectivity on the Preparation Method of Copper/α-alumina Catalysts in the Dehydrogenation of Cyclohexanol”,Appl. Catal. A: General,103, 233 (1993).

    Article  CAS  Google Scholar 

  • Chinchen, G. C., Hay, C. M., Vandervell, H. D. and Waugh, K. C.,“The Measurement of Copper Surface Areas by Reactive Frontal Chromatography”,J. Catal,103, 79 (1987).

    Article  CAS  Google Scholar 

  • Cubberley, A. H. and Mueller, M. B., “Equilibrium Studies on the Dehydrogenation of Primary and Secondary Alcohols. II. Cyclohexanol”,J. Am. Chem. Soc, June, 1535 (1947).

  • Jeon, G. S. and Chung, J. S., “Preparation and Characterization of Silica-supported Copper Catalysts for the Dehydrogenation of Cyclohexanol to Cyclohexanone”,Appl. Catal. A: General,115, 29 (1994).

    Article  CAS  Google Scholar 

  • Kobayashi, H., Takezawa, N., Minochi, C. and Takahashi, K., Dispersion of Copper Supported on Silica and Methanol Reforming Reaction”,Chem. Lett., 1197 (1980).

  • Minochi, C., Kobayashi, H. and Takezawa, N.,“The Catalytic Activities of Methanol Reforming Catalysts and Their Preparations”,Chem. Lett., 507(1979).

  • Monti, D. M., Wainwright, M. S., Trimm, D. L. and Cant, N. W.,“Kinetics of the Vapor-phase Hydrogenolysis of Methyl Formate over Copper on Silica Catalysts”,Ind. Eng. Chem. Prod. Res. Dev.,24, 397 (1985).

    Article  CAS  Google Scholar 

  • Sivaraj, C., Reddy, B. M. and Rao, P. K.,“Selective Dehydrogenation of Cyclohexanol to Cyclohexanone on Cu-ZnO-A12O3 Catalysts”,Appl. Catal,45, L11 (1988).

    Article  CAS  Google Scholar 

  • Sodesawa, T., “Dynamic Change in Surface Area of Cu in Dehydrogenation of Methanol over Cu-SiO2 Catalyst Prepared by Ion Exchange Method”,React. Kinet. Catal. Lett.,24, 259 (1984).

    Article  CAS  Google Scholar 

  • Sodesawa, T., Nagacho, M., Onodera, A. and Nozaki, F., “Dehydrogenation of Methanol to Methyl Formate over Cu-SiO2 Catalysts Prepared by Ion Exchange Method”,J. Catal,102, 460 (1986).

    Article  CAS  Google Scholar 

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Jeon, G.S., Seo, G. & Chung, J.S. Dehydrogenation of cyclohexanol to cyclohexanone over Cu/SiO2 catalysts : Dispersion and catalytic activity. Korean J. Chem. Eng. 13, 412–414 (1996). https://doi.org/10.1007/BF02705971

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  • DOI: https://doi.org/10.1007/BF02705971

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