Abstract
Two-component polyurethane flame retardant coatings were prepared using phosphorus-containing lactone modified polyesters (PLMPs) and polyisocyanate. PLMPs were synthesized by poly-condensation of dimethyl phenylphosphonate, a flame retardant component with polycaprolactone, adipic acid, and trimethylolpropane. PLMPs were prepared with dimethyl phenylphosphonate content from 10 to 20 wt%. It was found that various physical properties of these new flame retardant coatings were comparable to non-flame retardant coatings. The flammability of coatings depends strongly on the dimethyl phenylphosphonate content in PLMP. Coatings with 20 wt% dimethyl phenylphosphonate content did not burn in the vertical burning test.
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Tehranisa, M., Ryntz, R.A., Xiao, H.X., Kordomenos, P.I., and Frisch, K.C., “Urethane Acrylic Interpenetrating Polymer Networks for Coating Applications,”Journal of Coatings Technology,59, No. 746, 43 (1987).
Oldring, P.K.T. and Hayward, G.,Resins for Surface Coatings, Vol 3, pp. 27–31, Selective Industrial Training Associates, London, 1987.
Bhandari, S. and Chandra, S., “Fire-Retardant Coatings Based on Chlorinated Dehydrated Castor Oil Alkyd,”Paint India, 42, 397 (1992).
Haythornthwaite, D., “Burning Time with Flame Retardant Coatings,”Polymer Paint Col. J., 184, 282 (1994).
Park, H.S., Hahm, H.S. and Park, E.K., “Preparation and Characteristics of Two-Component Polyurethane Flame Retardant Coatings Using 2,3-Dibromo Modified Polyesters,”J. Appl. Polymer Sci., 61, 421 (1996).
Park, H.S., Keun, J.H., and Lee, K.S., “Syntheses and Physical Properties of Two-Component Polyurethane Flame-Retardant Coatings Using Chlorine-Containing Modified Polyesters,”J. Polymer Sci. (Part A), 34, 1455 (1996).
Park, C.H., Wu, J.P., Park, H.S., and Kim, S.K., “Syntheses and Characterizations of Two-Component Polyurethane Flame Retardant Coatings Using 2,4-Dichloro Modified Polyesters,”Journal of Coatings Technology,69, No. 875, 41 (1997).
Im, W.B., “Preparation and Characterization of Modified Polyesters/IPDI-Isocyanurate Polyurethane Flame Retardant Coatings Containing Chlorine and Phosphorus,” Ph.D. Dissertation, Myong Ji Univ., Yongin, Korea, 1998.
Nippon Kokan K.K., Jpn. Patent, 280,546 (1993).
Weil, E. and McSwigan, B., “Melamine Phosphates and Pyrophosphates in Flame Retardant Coatings,”Journal of Coatings Technology,66, No. 839, 75 (1994).
Kordomenos, P.I., Frisch, K.C., Xiao, H.X., and Sabbah, N., “Coating Compositions Based on Acrylic-Polyurethane Interpenetrating Polymer Networks,”Journal of Coatings Technology,57, No. 723, 23 (1985).
KS M 5000-2121, “Testing Method of Viscosity for Transparent Liquids,” Korea Industrial Standard Test Method, issued in 1990.
KS M 5000-1111, “Preparation of Steel Panels for Organic Coating Materials,” Korea Industrial Standard Test Method, issued in 1990.
KS M 5000-1112, “Method of Made for Tin Panel for Use in Paint, Varnish, Lacquer, and Related Materials,” Korea Industrial Standard Test Method, issued in 1990.
KS M 5000-3421, “Testing Method for Heat Resistance of Dried Film of Paint, Varnish, Lacquer, and Related Materials,” Korea Industrial Standard Test Method, issued in 1984.
KS M 5000-3331, “Testing Method for Flexibility for Organic Coating Materials,” Korea Industrial Standard Test Method, issued in 1990.
JIS K 5400, “General Testing Method of Coatings,” Japan Industrial Standard Test Method, issued in 1990.
KS M 5000-3312, “Testing Method of 60° Specular Gloss of Paints,” Korea Industrial Standard Test Methods, issued in 1990.
FS 141-6152, “Abrasion Resistance (Taber Abraser),” Federal Test Method Standard, issued in 1986.
KS M 5000-3221, “Testing Method for Accelerated Yellowness of Dried Film of Paint, Varnish, Lacquer, and Related Materials,” Korea Industrial Standard Test Method, issued in 1990.
KS M 5000-3031, “Testing Method for Lightness Index Difference of Paint & Color,” Korea Industrial Standard Test Method, issued in 1989.
KS A 0063, “Method for Specification of Color Differences for Opaque Materials,” Korea Industrial Standard Test Method, issued in 1996.
Union Carbide Co.,Tone Polyols for High-Performance Coatings, Adhesives, and Elastomers, 2nd Ed., pp. 1–7, Union Carbide Chem. and Plastic Tech. Co., New York, 1989.
Serini, V., Nouvertne, W., and Freitag, D., U.S. Patent, 4,481,338 (1984).
Patton, T.C.,Paint Flow and Figment Dispersion: A Rheological Approach to Coating and Ink Technology, 2nd Ed., Wiley, New York, 1979.
Lanson, H.J., inEncyclopedia of Polymer Science and Engineering, Kroschwitz, J.I. (Ed.), 2nd Ed., Vol. 1, p. 656, Wiley, New York, 1985.
Gardner, R.J. and Martin, J.R., “Effect of Relative Humidity on the Mechanical Properties of Poly(1,4-Butylene Terephthalate),”J. Appl. Polymer Sci., 25, 2353 (1980).
Keun, J.H. and Park, H.S., “A Study on Preparation and Fire-Retardant Behavior of Phosphate Type Emulsified Fire Proofing Agent for Synthetic Fibers,”J. Kor. Oil Chem. Soc., 11 (1), 45 (1994).
Calbo, L.J.,Handbook of Coating Additives, Vol. 1, p. 125, Marcel Dekker, New York, 1992.
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Dept. of Chem. Eng., Yongin 449-728, Korea.
Ansan 425-110, Korea.
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Park, HS., Kwon, SY., Seo, KJ. et al. Preparation and physical properties of polyurethane flame retardant coatings using phosphorus-containing lactone modified polyesters. Journal of Coatings Technology 71, 59–65 (1999). https://doi.org/10.1007/BF02697979
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DOI: https://doi.org/10.1007/BF02697979