Skip to main content
SpringerLink
Log in

Partial miscibility in water-nicotine and water β-picoline systems

  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

The significant structure theory of liquids has been applied to the partially miscible systems, of which the temperature-composition phase diagrams are of closed loop type.

In this paper, the sublimation energy of a mixture is expressed as a quadratic form of surface area fractions of components, and the energy correction parameter between one component and the other is assumed to be a second order function of temperature for simplicity, although it is a higher order function of temperatures and compositions. The calculated partial miscibilities are in good agreement with the experiment.

Considered mixture systems are water-nicotine and waterβ picoline systems.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Bernstein, R.E., Cruz, CA., Paul, D.R. and Barlow, J.W.: Macromolecules,10, 681 (1977).

    Article  CAS  Google Scholar 

  2. “Landolt-Börnstein, Zahlen Werte und Functionen aus Physik, Chemie, Astronomie, Geophysik und Technik”, Band II, Teil III, Springer-Verlag, Berlin (1960).

  3. Eyring, H. and Jhon, M.S.: “Significant Liquid Structures”, John Wiley, New York (1969).

    Google Scholar 

  4. Liang, K., Eyring, H. and Marchi, R.: Proc. Natl. Acad. Sei. U.S.A.,52, 1107 (1964).

    Article  CAS  Google Scholar 

  5. Ma, S. and Eyring, H.: J. Chem. Phys.,42, 1920 (1965).

    Article  CAS  Google Scholar 

  6. Miner, B.A. and Eyring, H.: Proc. Natl. Acad. Sci. U.S.A.,53, 1227 (1965).

    Article  CAS  Google Scholar 

  7. Lee, S.H., Jhon, M.S. and Eyring, H.: Proc. Natl. Acad. Sci. U.S.A.,74, 10 (1977).

    Article  CAS  Google Scholar 

  8. Jung, H.Y. and Jhon, M.S.: J. Polym. Sci., Polym. Chem. Ed., in press.

  9. Jhon, M.S., Grosh, J., Ree, T. and Eyring, H.: J. Chem. Phys.,44, 1465 (1966).

    Article  CAS  Google Scholar 

  10. Scott, D.W., Good, W.D., Guthrie, G.B., Todd, S.S., Hossenlopp, I.A., Osborn, A.G. and McCullough, J.P.: J. Phys.Chem.,67, 685 (1963).

    Article  CAS  Google Scholar 

  11. “The Scientific Papers of J. Williard Gibbs”, Vol. I, Dover, NewYork (1961).

  12. McQuarrie, D.A.: “Statistical Mechanics”, Harper & Row, New York (1976).

    Google Scholar 

  13. “International Critical Tables”, Vol. 3, McGraw-Hill, New York (1928).

  14. Bondi, A.: “Physical Properties of Molecular Crystals, Liquids, and Glasses”, John Wiley, New York (1968).

    Google Scholar 

  15. Cho, H.K., Yoon, S.C. and Jhon, M.S.: J. Polym. Sci., Polym. Chem. Ed.,20, 1247 (1982).

    Article  CAS  Google Scholar 

  16. Koo, C.H. and Kim, H.S.: J. Korean Chem.Soc,9, 134 (1965).

    CAS  Google Scholar 

  17. Bak, B., Hansen, L. and Rastrup-Andersen, J.: J. Chem. Phys.,22, 2013 (1954).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Korea Advanced Institute of Science and Technology, Cheong Ryang Ri, P.O. Box 150, Seoul

    Hae Young Jung & Mu Shik Jhon

Authors
  1. Hae Young Jung
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mu Shik Jhon
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jung, H.Y., Jhon, M.S. Partial miscibility in water-nicotine and water β-picoline systems. Korean J. Chem. Eng. 1, 59–63 (1984). https://doi.org/10.1007/BF02697419

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02697419

Keywords

Search

Navigation