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Application of conducting polymers in corrosion protection

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Journal of Coatings Technology

Abstract

The use of oxides, such as chromates, is highly effective in corrosion protection. Scientists are looking at alternative materials to replace environmentally hazardous materials, e.g., chromates. One of the group of materials identified as corrosion inhibiting are intrinsically conducting polymers.

This paper focuses on the use of ICPs as a possible corrosion inhibitive substance. This paper also reviews literature on the research of different groups on the use of polyaniline and other conducting polymers as corrosion inhibitors. Intrinsically conducting polymers, especially poly-aniline, are being studied with great interest. Studies indicate that they have the potential of replacing some of the currently available materials.

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References

  1. Heeger, A.J., Smith, P., Fizzi, A., Moulton, J., Pakbaz, K., and Rughooputh, S., “Recent Progress in Conducting Polymers—Opportunities for Science and Opportunities for Technology,”Synthetic Metals, 41–43, 1027–1032 (1991).

    Article  Google Scholar 

  2. Alcacer, L.,The Physics and Chemistry of Low Dimensional Solids, D. Reidel Publ. Co., Boston, MA, 1980.

    Google Scholar 

  3. Seymour, R.B. (Ed.),Conductive Polymers, Plenum Press, NY, 1981.

    Google Scholar 

  4. Schoch, K.F., “Electrically Conductive Polymers and Their Applications,”IEEE Electrical Insulation Magazine, 2, No. 1, 20–26, (1986).

    Article  Google Scholar 

  5. Kinlen, P.J. and Silverman, D.C., Monsanto Interin Report, No. MSL 13430 (1994).

  6. Zipperling Kessler & Co., Polyaniline Technical Literature (1995).

  7. Diaz, A.F. and Logan, J.A., Journal of Electroanalytical Chemistry, Vol. 111, 111 (1980).

    Article  CAS  Google Scholar 

  8. Hung, L.C.P., “Chemical Preparation of Electrically Conducting Polyaniline/Poly(vinyledene chloride) Composite Film,” UMR Thesis, 1990.

  9. Epstein, A.J., and MacDiarmind, A.G., “Polyaniline: Solutions, Films, and Oxidation State,”Proc. Faraday Society, Faraday Trans, 1989.

  10. DeBerry, D.W. and Viehbeck, A., “Fundamental Aspects of Corrosion Protection by Surface Modification,” McCafferty, E., Clayton, C.R., and Oudar, J. (Ed.),The Electrochemical Society Softbound Proceedings Series, 308–323, Pennington, NJ, 1984.

  11. DeBerry, D.W., “Modification of the Electrochemical and Corrosion Behavior of Stainless Steel with an Electroactive Coatings,”J. Electrochem. Soc., 132, No. 5, 1022 (1985).

    Article  CAS  Google Scholar 

  12. Ahmad, N.H. and MacDiarmid, A.G.,Bulletin of American Physics Society, 32, No. 3, 548 (1987).

    Google Scholar 

  13. Deng, Z., Smyrl, W.H., and White, H.W., “Stabilization of Metal-Metal Oxide Surfaces Using Electroactive Polymer Films,”J. Electrochem. Soc., 136, No. 8, 2152 (1989).

    Article  CAS  Google Scholar 

  14. Deng, Z. and Smyrl, W.H., “Application of Electroactive Films in Corrosion Protection,”J. Electrochem. Soc., 138, No. 7, 1911 (1991).

    Article  CAS  Google Scholar 

  15. Thompson, K.G., Bryan, C.J., Benicewicz, B.C., and Wrobleski, D.A., “Los Alamos National Laboratory, Report LA-UR-92-360,” “Corrosion Resistant Coatings From Conducting Polymers,”ACS Polymer Preprints, 35, No. 1, 265 (1994).

    Google Scholar 

  16. Beck, F., “A Novel Way to Corrosion Protection: The Electrochemical Deposition of Conducting Polymers,”Metalloberflaeche, Vol. 46, No. 4, 177 (1992).

    CAS  Google Scholar 

  17. Troch-Nagels, G., Winand, R., Weymeersch, A., and Renard, L., “Electron Conducting Organic Coating of Mild Steel by Electropolymerization,”J. Applied Electrochem., 22, 756 (1992).

    Article  CAS  Google Scholar 

  18. Sekine, I., Kohoara, K., Sugiyama, T., and Yuasa, M.,J. Electrochem. Soc., 1398, 2090 (1992).

    Google Scholar 

  19. Sathiyanarayan, S., Balakrishnan, K., Dhawan, S.K., and Trivedi, D.C.,Corrosion Science, 33, 1831 (1992).

    Article  Google Scholar 

  20. Geskin, V.M., “Electrodeposition of Polyaniline Onto Non-Noble Metals II. Nickel,”J. Chem. Physics, 89, 1221 (1992).

    CAS  Google Scholar 

  21. Wessling, B., “Passivation of Metals by Coatings with Polyaniline: Corrosion Potential Shift and Morphological Changes,”Adv. Materials, 6, No. 3, 226 (1994).

    Article  CAS  Google Scholar 

  22. Lu, W.K., Elsenbaumer, R.L., and Wessling, B., “Corrosion Protection of Mild Steel by Coatings Containing Polyaniline,” paper at the ICSM, Seoul, 1994.

  23. Jasty, S. and Epstein, A.J., “Corrosion Prevention Capability of Polyaniline (Emeraldine Base and Salt: An XPS Study),”ACS Polymer Preprints, 36, 565 (1995).

    Google Scholar 

  24. Wei, Y., Wang, J., Jia, X., Yeh, J., and Spellane, P.,ACS Polymer Preprints, 36, 563–564 (1995).

    Google Scholar 

  25. Sitaram, S.P., Yu, P., O’Keefe, T.J., and Stoffer, J.O.,ACS Polymer Preprints, 1996.

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Materials Research Center, Straumanis Hall, Rolla, MO 65401-0249.

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Sitaram, S.P., Stoffer, J.O. & O’Keefe, T.J. Application of conducting polymers in corrosion protection. Journal of Coatings Technology 69, 65–69 (1997). https://doi.org/10.1007/BF02696146

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