Abstract
Antiferromagnetic spin-flop transitions in a series of λ-(BETS)2FeBrxCl4-x are observed using piezoresistive AFM microcantilever. The measurements are carried out on a tiny single crystal using a sample rotator and the easy axis changes with increasing the bromine content x. The Néel temperature and spin-flop transition field also rise with increasing the bromine content x, suggesting an enhancement of π-d interactions by replacement of chlorine with bromine atoms in this mixed-halide anion system.
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H. Kobayashi, H. Tomita, T. Naito, A. Kobayashi, F. Sakai, T. Watanabe and P. Cassoux,J. Am. Chem. Soc. 118, 368 (1996).
M. Tokumoto, T. Naito, H. Kobayashi, A. Kobayashi, V. N. Laukhin, L. Brossard, and P. Cassoux,Synth. Metals 86, 2161 (1997).
H. Kobayashi, H-B Cui and A. Kobayashi,Chem. Rev. 104, 5265 (2004).
T. Mori and M. Katsuhara,J. Phys. Soc. Jpn. 71, 826 (2002).
H. Akutsu, E. Arai, H. Kobayashi, H. Tanaka, A. Kobayashi and P. Cassoux,J. Am. Chem. Soc. 119, 12681 (1997).
H. Akutsu, K. Kato, E. Ojima, H. Kobayashi, H. Tanaka, A. Kobayashi and P. Cassoux,Phys. Rev. B58, 9294 (1998).
M. Tokumoto, H. Tanaka, T. Otsuka, H. Kobayashi, and A. Kobayashi,Polyhedron 24, 2793 (2005)
H. Takahashi, K. Ando, Y. Shirakawabe, Ultramicroscopy91, 63 (2002)
T. Sasaki, H. Uozaki, S. Endo, and N. Toyota,Synth. Metals 120, 759 (2001).
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Tanaka, H., Hara, S., Tokumoto, M. et al. Observation of antiferromagnetic spin-flop transition in λ-type BETS salts using AFM microcantilever. J Low Temp Phys 142, 605–608 (2006). https://doi.org/10.1007/BF02679580
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DOI: https://doi.org/10.1007/BF02679580