Abstract
The presence of cardanol in cashew seed and germ oils was detected by using a combination of the thin layer chromatography (TLC) and gas liquid chroma-tography (GLC) techniques with infrared spectro-scopy (IR) and mass spectrometry (MS). The oils were extracted from cashew nuts obtained by the Oltremare process (heating the nuts in cashew nut shell liquid bath at 180 C for 100–120 sec). The cardanol content was about 40 mg/100 ml of germ oil and 20 mg/100 ml of seed oil. The four cardanol components were found in the following percentages: 3-(pentadecyl)-phenol (II), 3.0%; 3-(8-pentadecenyl)-phenol (III), 55.7%;3-(8,11-pentadecadienyl)-phenol (IV), 24.2%; and 3-(8,l l,14-pentadecatrienyl)-phenol (V), 17.1%, respectively. Because a constant distribu-tion of the four cardanol components was found both in the seed and in the germ oils, it was suggested that cardanol is not a natural component of germ and seed oils, but is derived from the cashew nut-shell liquid during the processing of the nuts.
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Strocchi, A., G. Lercker, U. Pallotta, and P. Capella, Sci. Technol. Alim. 6:357 (1974).
Baker, H.J., and N.H. Haack, Rev. Trav. Chim. 60:611 (1941).
Sletzinger, M., and C.R. Dawson, J. Am. Chem. Soc. 68:345 (1946).
Sletzinger, M., and C.R. Dawson, J. Org. Chem. 14:670 (1949).
Izzo, P.T., and C.R. Dawson, Ibid. 14:1039 (1949).
Sletzinger, M., and C.R. Dawson, Ibid. 14:849 (1949).
Symes, W.F., and C.R. Dawson, J. Am. Chem. Soc. 75:4952 (1953).
Loev, B., and C.R. Dawson, Ibid. 80:643 (1958).
Baiao, Esteves, A., C. Amaro De Neves, J.A. Pereira, Garcia de Orta, Lisboa, 13(4):605 (1965).
Piretti, M.V., P. Capella, U. Pallotta, Riv. Ital. Sostanze Grasse 46:652 (1969).
Strocchi, A., G. Lercker, and G. Losi, Rev. Kr. des Corps Gras. 20:625 (1973).
Capella, P., and C.M. Zorzut, Anal. Chem. 40:1458 (1968).
Budzikiewics, H., C. Djerassi, and D.H. Williams, in “Mass Spectrometry of Organic Compounds,” Holden Day Inc. San Francisco, CA, 1967, p. 117.
Bellamy, L.J., “The Infrared Spectra of Complex Molecules,” Chapman and Hall, London, 1975, p. 83.
Szymansky, H.A., “Interpreted Infrared Spectra,” Plenum Press Data Division, New York, 1967, Vol. 3, p. 28.
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Strocchi, A., Lercker, G. Cardanol in germ and seed oils extracted from cashew nuts obtained by the oltremare process. J Am Oil Chem Soc 56, 616–619 (1979). https://doi.org/10.1007/BF02679334
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DOI: https://doi.org/10.1007/BF02679334