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New amphoteric surfactants containing a 2-hydroxyalkyl group: II. the dependence of physicochemical properties on the pH value for N-(2-hydroxyethyl)-N-(2-hydroxyalkyl)-β-alanines

  • Published:
Journal of the American Oil Chemists’ Society

Abstract

The dependence of physicochemical properties on the pH of micellar solutions for N-(2-hydroxyethyl)-N-(2-hydroxyalkyl)-β alanines (HAA) was studied by means of a differential titration method (DTM), Fourier transform infrared (FTIR) spectra, and measurements of critical micelle concentration, surface tension, and foaming power. The aspect of the dissociation of HAA was pursued by DTM. The mutual transformation among cationic, zwitterionic, and anionic forms with the change of pH range was confirmed by FTIR spectroscopy. The micelle formation energy was determined at each pH value. Further, the dependence of surface active properties on the pH value for the adducts of ethylene oxide to Na-HAA was also investigated.

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References

  1. Takai, M., H. Hidaka, and M. Moriya, JAOCS 56:537 (1979).

    CAS  Google Scholar 

  2. Ulsperger, E., Fette, Seifen, Anstrichm. 68:964 (1966).

    Article  CAS  Google Scholar 

  3. Hidaka, H., T. Furuta, and T. Ishikawa, Yukagaku 27:304 (1978).

    CAS  Google Scholar 

  4. Hidaka, H., Y. Kawajiri, and S. Noro, —Ibid. 28:190 (1979).

    CAS  Google Scholar 

  5. Kita, H., S. Otsuka, and S. Arai, Symposium Report of Jpn. Oil Chem. Soc. on the 20th years Establishment, 1972, p. 73.

  6. “Data for Biochemical Research,” 2nd Ed., Edited by R.M.C. Dawson, D.C. Elliott, W.H. Elliotte, and K.M. Jones, Claredon Press, Oxford, 1969, p. 4.

  7. Tukushima, K., T. Onishi, T. Shimanouchi, and S. Mizushima, Spectrochimica Acta 15:236 (1959).

    Article  Google Scholar 

  8. Tokiwa, F., and K. Ohki, Yukagaku 19:901 (1970).

    CAS  Google Scholar 

  9. Okumura, T., K. Tajima, and T. Sasaki, Bull. Chem. Soc Jpn. 47:1067 (1974).

    Article  CAS  Google Scholar 

  10. Corkill, J.M., K.W. Gemmel, J.F. Goodman, and T. Walker, Trans. Faraday Soc. 66:1817 (1970).

    Article  Google Scholar 

  11. Tokiwa, F., and K. Ohki, J. Phys. Chem. 70:3437 (1966).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Science and Engineering, Meisei University, 337Hodokubo, Hino-shi, 191, Tokyo, Japan

    H. Hidaka

  2. Miyoshi Oil & Fat Co. Ltd., 66-1, Horikiri 4-chome, Katsushika-ku, 124, Tokyo, Japan

    M. Moriya & M. Takai

Authors
  1. H. Hidaka
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  2. M. Moriya
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  3. M. Takai
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Hidaka, H., Moriya, M. & Takai, M. New amphoteric surfactants containing a 2-hydroxyalkyl group: II. the dependence of physicochemical properties on the pH value for N-(2-hydroxyethyl)-N-(2-hydroxyalkyl)-β-alanines. J Am Oil Chem Soc 56, 914–917 (1979). https://doi.org/10.1007/BF02676369

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  • DOI: https://doi.org/10.1007/BF02676369

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