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Gas-liquid chromatography of fatty derivatives

III. Analysis of fatty amines

  • Technical
  • Published:
Journal of the American Oil Chemists’ Society

Summary

The separation of fatty amines has been carried out with nonpolar substrates on solid supports of Chromosorb and Chromosorb W, which were previously treated with potassium hydroxide to overcome adsorptivity. In this manner well-resolved symmetrical peaks are obtained. Untreated supports give peaks which trail and prohibit precise quantitative measurements. Both Apiezon L on Chromosorb W and Silicone Grease on Chromosorb have proved effective, the latter at 176°C. and the former at 225°C. Relative detector sensitivity factors have been determined for the amines C8 to C18, thus permitting accurate analyses. The relative response for primary alkyl fatty amines is a linear function of molecular weight.

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References

  1. Cropper, F. R., and Heywood, A., in “Vapour Phase Chromatography,” London, 1956, edited by Desty, D. H., Academic Press, New York, 1957.

    Google Scholar 

  2. Decora, A. W., and Dineen, G. U., presented at ISA’s 2nd International Symposium on Gas Chromatography, Michigan State University, June, 1959.

  3. Dimick, K. P.,et al., data presented at the American Oil Chemists’ Society meeting, Los Angeles, Calif., September 28–30, 1959.

  4. James, A. T., Biochem. J.,52, 242 (1952).

    CAS  Google Scholar 

  5. James, A. T., Martin, A. J., and Smith, G. H., Biochem. J.,52, 238 (1952).

    CAS  Google Scholar 

  6. Johns, T., Beckman Gas Chromatography Manual, Bulletin 756, Beckman Instruments Inc., 1959.

  7. Johnns T., in “Gas Chromatography,” edited by Coates, V. J., Noebels, H. J., and Fogerson, I. S., Academic Press, New York, 1958.

    Google Scholar 

  8. Killheffer, J. V.,et al., data presented at the American Chemical Society meeting, Atlantic City, N. Y., September 13–18, 1959.

  9. Knight, H. S., Anal. Chem.,30, 2030 (1958).

    Article  CAS  Google Scholar 

  10. Link, W. E., Hickman, H. M., and Morrissette, R. A., J. Am. Oil Chemists’ Soc.,36, 20 (1959).

    CAS  Google Scholar 

  11. Link, W. E., Hickman, H. M., and Morrissette, R. A., J. Am. Oil Chemists’ Soc.,36, 300 (1959).

    Article  CAS  Google Scholar 

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Author information

Authors and Affiliations

  1. Archer-Daniels-Midland Company, Minneapolis, Minnesota

    W. E. Link & R. A. Morrissette

  2. Atlas Powder Company, Wilmington, Delaware

    A. D. Cooper & C. F. Smullin

Authors
  1. W. E. Link
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  2. R. A. Morrissette
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  3. A. D. Cooper
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  4. C. F. Smullin
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Additional information

The application of gas chromatography described in this paper was conceived and developed independently and simultaneously in the respective research laboratories of these two companies.

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Link, W.E., Morrissette, R.A., Cooper, A.D. et al. Gas-liquid chromatography of fatty derivatives. J Am Oil Chem Soc 37, 364–366 (1960). https://doi.org/10.1007/BF02672470

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  • DOI: https://doi.org/10.1007/BF02672470

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