Abstract
This article introduces a series of studies of phase transformations in maraging steels. Atom-probe field-ion microscopy (APFIM) was the main research technique employed. Hardness measurements, transmission electron microscopy (TEM), and thermochemical calculations were also used. The composition and morphology of precipitates in the commercial-grade C-300 steel were compared for different aging times at 510 °C to investigate the aging sequence. Both Ni3Ti and Fe7Mo6 were found to contribute to age hardening. The decomposition starts with the formation of small Mo-enriched Ni3Ti particles at very short aging times. The Fe7Mo6 phase forms at a later stage of aging. The matrix concentrations of both Ti and Mo were measured and were found to be low after standard aging conditions. The observation of the Fe7Mo6 μ phase is supported by thermochemical calculations. Austenite reversion has been found at the aging temperature, and its composition approaches the predicted equilibrium composition after 8 hours of aging.
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S. Floreen:Metall. Rev., 1968, vol. 13, pp. 115–28.
R.F. Decker and S. Floreen: inMaraging Steels: Recent Developments and Applications, R.K. Wilson, ed., TMS-AIME, Warrendale, PA, 1988, pp. 1–38.
A. Magnee, J.M. Drapier, J. Dumont, D. Coutsourdis, and L. Habraken:Cobalt-containing High-strength Steels: A Critical Review of the Physical Metallurgy of Cobalt-containing High- strength Steels, and a Survey of Their Processing, Properties and Uses, Centre D’Information Du Cobalt, Brussels, 1974, pp. 50–123.
K. Ogawa, M. Fukamachi, and Y. Kawabe:Nippon Kinzoku Gakkaishi, 1983, vol. 47, pp. 863–67.
F. Edneral, V.B. Dmitriev, A.N. Kudryavtsev, and V.V. Rusanenko:Dokl. Akad. NaukSSSR, 1984, vol. 278, pp. 612–15.
A.N. Kudryavtsev and A.F. Edneral:Dokl. Akad. Nauk SSSR, 1981, vol. 261, pp. 611–15.
M. Fukamachi, Y. Kawabe, K. Nadazawa, and S. Muniki:Nippon Kinzoku Gakkaishi, 1983, vol. 47, pp. 237–42.
J.R. Mihalisin and C.G. Bieber:J. Met., 1966, vol. 18, pp. 1033–36.
V.K. Vasudevan, S.J. Kim, and C.M. Wayman: inMaraging Steels: Recent Development and Applications, R.K. Wilson, ed., TMS-AIME, Warrendale, PA, 1988, pp. 283–94.
V.K. Vasudevan, S.J. Kim, and C.M. Wayman:Metall. Trans. A, 1990, vol. 21A, pp. 2655–68.
M.K. Miller and G.D.W. Smith:Atom Probe Microanalysis: Principles and Applications to Materials Problems, MRS, Pittsburgh, PA, 1989.
A.F. Edneral, V.I. Kirienko, and L.P. Potapov:Dokl. Akad. Nauk SSSR, 1973, vol. 213, pp. 567–68.
A.P. Khlyntsev, A.N. Kudryavtsev, L.P. Potapov, and V.I. Kirienko:Fiz. Met. Metalloved., 1979, vol. 47, pp. 815–20.
A. Cerezo, C.R.M. Grovenor, M.G. Hetherington, W. Sha, B.A. Shollock, and G.D.W. Smith:Mater. Charact., 1990, vol. 25, pp. 143–56.
W. Sha, A. Cerezo, and G.D.W. Smith:J. Phys. Colloq., 1989, vol. 50-C8, pp. 407–12.
W. Sha, A. Cerezo, and G.D.W. Smith:Surf. Sci., 1991, vol. 246, pp. 286–92.
W. Sha, G.D.W. Smith, and A. Cerezo:Surf. Sci., 1992, vol. 266, pp. 378–84.
W. Sha, A. Cerezo, and G.D.W. Smith:Scripta Metall. Mater., 1992, vol. 26, pp. 517–28.
A. Gemperle, J. Gemperlová, W. Sha, and G.D.W. Smith:Mater. Sci. Technol., 1992, vol. 8, pp. 546–54.
D.M. Vanderwalker: inMaraging Steels: Recent Development and Applications, R.K. Wilson, ed., TMS-AIME, Warrendale, PA, 1988, pp. 255–68.
D.M. Vanderwalker:Metall. Trans. A, 1987, vol. 18A, pp. 1191–14.
C. Servant, G. Maeder, and G. Cizeron:Metall. Trans. A, 1975, vol. 6A, pp. 981–90.
C.F. Hickey, Jr., D.W. Dix, and D. Kagan:Mechanical Property Characterization of VascoMax T-300, United States Army Materials Technology Laboratory Report, MTL TR 89-81, p. 5.
D.T. Peters:Trans. ASM, Trans. Q., 1968, vol. 61, pp. 62–74.
J.M. Papazian:J. Microsc, 1972, vol. 95, p. 429.
W. Sha, A. Cerezo, and G.D.W. Smith:Metall. Trans. A, 1993, vol. 24A, pp. 1251–56.
J.B. Lecomte, C. Servant, and G. Cizeron:J. Mater. Sci., 1985, vol. 20, pp. 3339–52.
W.A. Spitzig, J.M. Chilton, and C.J. Barton:Trans. ASM, 1968, vol. 61, pp. 635–39.
M.L. Schmidt: inMaraging Steels: Recent Developments and Applications, R.K. Wilson, ed., TMS-AIME, Warrendale, PA, 1988, pp. 213–36.
B. Sundman, B. Jansson, and J.-O. Andersson:CALPHAD, 1985, vol. 9, p. 150.
Binary Phase Diagrams, 2nd ed., T.B. Massalski, ed., ASM, Metals Park, OH, 1990.
W. Sha, A. Cerezo, and G.D.W. Smith:Metall. Trans. A, 1993, vol. 24A, pp. 1241–49.
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Formerly Graduate Student with the Department of Materials, Oxford University.
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Sha, W., Cerezo, A. & Smith, G.D.W. Phase chemistry and precipitation reactions in maraging steels: Part I. Introduction and study of Co-containing C-300 steel. Metall Trans A 24, 1221–1232 (1993). https://doi.org/10.1007/BF02668190
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DOI: https://doi.org/10.1007/BF02668190