Abstract
The activity coefficients of FetO in CaO-Al2O3 and CaO-Al2O3-SiO2 slags with 0.01 to 5 mass pct FetO were determined at 1873 K from the data obtained in the present and previous slag-metal experiments, using an alumina or lime crucible. It was found that the activity coefficients of FetO obeyed a dilute solution law and increased with increasing the content of SiO2. Based on the findings pertaining to the activity coefficient, the values for the activities of SiO2 and Al2O3 in CaO-Al2O3-SiO2 slags were assessed.
Similar content being viewed by others
References
F. Tamura and H. Suito:Metall. Trans. B, 1993, vol. 24B, pp. 121–30.
T. Kimura and H. Suito:Metall. Mater. Trans. B, 1994, vol. 25B, pp. 33–42.
S.W. Cho and H. Suito:Iron Steel Inst. Jpn. Int., 1994, vol. 34, pp. 177–85.
J. Tanabe and H. Suito:Metall. Mater. Trans. B, in press.
R. Inoue and H. Suito:Current Advances Mater. Processes, 1993, vol. 6, p. 1059 ; Steel Res., 1994, vol. 65 (10).
R.H. Rein and J. Chipman:Trans. TMS-AIME, 1965, vol. 233, pp. 415–25.
H. Suito, H. Inoue, and R. Inoue:Iron Steel Inst. Jpn. Int., 1991, vol. 31, pp. 1381–88.
R. Inoue and H. Suito:Trans. Jpn. Inst. Met., 1991, vol. 32, pp. 1164–69.
R. Inoue and H. Suito:Metall. Trans. B, 1992, vol. 23B, pp. 613–21.
J.F. Elliott, M. Gleiser, and V. Ramakrishna:Thermochemistry for Steelmaking, Addison-Wesley Publishing Co., Reading, MA, 1963, vol. 2..t
G.K. Sigworth and J.F. Elliott:Met. Sci., 1974, vol. 8, pp. 298–310.
H. Suito and R. Inoue:Trans. Iron Steel Inst. Jpn., 1984, vol. 24, pp. 301–07.
K. Tomioka and H. Suito:Steel Res., 1992, vol. 63, pp. 1–6.
S.R. Mehta and F.D. Richardson:J. Iron Steel Inst., 1965, vol. 203, pp. 524–28.
D.A.R. Kay and J. Taylor:Trans. Faraday Soc, 1960, vol. 56, pp. 1372–83.
B. Ozturk and R.J. Fruehan:Metall. Trans. B, 1987, vol. 18B, pp. 746–49.
F.C. Langenberg, H. Kaplan, and J. Chipman: inPhysical Chemistry of Steelmaking, J.F. Elliott, ed., John Wiley and Sons, New York, NY, 1958, pp. 65–67.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Lee, K.R., Suito, H. Activities of FetO in CaO-Al2O3-SiO2-FetO (<5 pct) slags saturated with liquid iron. Metall Mater Trans B 25, 893–902 (1994). https://doi.org/10.1007/BF02662771
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02662771