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A novel quasi-dimeric oxidation product of (+)-catechin from lipid peroxidation

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Journal of the American Oil Chemists Society

Abstract

A novel quasi-dimeric oxidation product of (+)-catechin, formed during the radical-scavenging reaction that prevents lipid peroxidation, was isolated by chromatography, and its structure was elucidated by infrared, ultraviolet and1H and13C nuclear magnetic resonance spectra and mass spectrometry. It was 5′-[3-[3,4-(3′,5′-dihydroxy) benzo-8-oxo-2,7-dioxabicyclo [4.4.0] deca-3,9-dien-10-yl]acryloyl]-(+)-catechin. It is an unusual type of dimer of flavan-3-ol derivatives, which is different from the naturally formed dimer, procyanidin.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Education, Yamanashi University, Takeda, Kofu, 400, Yamanashi, Japan

    Yuko Hirose

  2. Department of Natural Science, Osaka Women’s University, Daisen-cho, Sakai, 590, Osaka, Japan

    Hiroshi Yamaoka

  3. Department of Agricultural Chemistry, College of Agriculture, University of Osaka Prefecture, Mozuume-machi, Sakai, 591, Osaka, Japan

    Mitsuru Nakayama

Authors
  1. Yuko Hirose
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  2. Hiroshi Yamaoka
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  3. Mitsuru Nakayama
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Hirose, Y., Yamaoka, H. & Nakayama, M. A novel quasi-dimeric oxidation product of (+)-catechin from lipid peroxidation. J Am Oil Chem Soc 68, 131–132 (1991). https://doi.org/10.1007/BF02662334

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  • DOI: https://doi.org/10.1007/BF02662334

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