Abstract
Volatile odor components of winterized and undeodorized menhaden(Brevoortia tyrannus) oil were characterized by dynamic headspace concentration on a porous polymer trap, thermal desorption, cryogenic focusing, high resolution gas chromatography, mass spectrometry and chromatography-coupled descriptive odor evaluation. Many volatile odor components derived from lipid oxidation in the fish oil were identified. These included, among others, short-chain saturated and unsaturated aldehydes and ketones, as well as short-chain carboxylic acids. The former imparted greasy, oily, oxidized oil and green grassy or green plant-like odors, and the latter gave rather objectionable sweaty odors. Normal alkanes were detected as major volatiles without significant odors. The odor-significant volatile components may be used as specific flavor quality markers to determine deodorization efficiency on crude fish oil and to monitor flavor stability of purified oils. This combined analytical approach can be readily applied to the study of volatile components in other oils.
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References
Kinsella, J.E.,Food Tecknol.40:89 (1986).
Levy, R.I.,Am. J. Cardiol. 54:1c (1984).
Stansby, M.E.J. Am. Oil Chem. Soc. 48:820 (1971).
Stansby, M.E.,Ibid.50:220k (1973).
Chipault, J.R.,Hormel Inst. Univ. Minn. Ann. Rpt., 1956, pp. 61–65.
Chipault, J.R.,Ibid.J. Am. Oil Chem. Soc. 1959, pp. 7–8.
Chipault, J.R.,Ibid. J. Am. Oil Chem. Soc. 1960, pp. 7–8.
Badings, H.T.,Neth. Milk Dairy J. 24:177 (1970).
Crawford, L., and M.J. Kretsch,J. Food Sci. 41:1470 (1976).
Noble, A.C., and W.W. Nawar,J. Am. Oil Chem. Soc. 48:800 (1971).
Dupuy, H.P., E.T. Rayner and J.I. Wadsworth,Ibid. 53:628 (1976).
Dupuy, H.P., E.T. Rayner, J.I. Wadsworth and M.G. Legendre,Ibid. 54:445 (1977).
Warner, K., CD. Evans, G.R. List, H.P. Dupuy, J.I. Wadsworth and G.E. Goheen,Ibid. 55:252 (1978).
Legendre, M.G., G.S. Fisher, W.H. Schuller, H.P. Dupuy and E.T. Rayner,Ibid.56:552 (1979).
Dupuy, H.P, GJ. Flick, M.E. Bailey, A.J. St. Angelo, M.G. Legendre and G. Sumrell,Ibid. 62:1090 (1985).
Suzuki, J., and M.E. Bailey,J. Agric. Food Chem. 33:343 (1985).
Dupuy, H.P., GJ. Flick Jr., A.J. St. Angelo and G. Sumrell,J. Am. Oil Chem. Soc. 63:905 (1986).
Min, D.B., and J-G. Kim, inFlavor Chemistry of Fats and Oils, edited by D.B. Min and T.H. Smouse,American Oil Chemists’ Society, Champaign, IL, 1985, p. 241.
Min, D.B.,J. Food Sci. 46:1453 (1981).
Jackson, H.W., and DJ. Giacherio,J. Am. Oil Chem. Soc. 54:458 (1977).
Jackson, H.W, G.K. Mirmira and W.M. Wagner,Ibid.63:117 (1986).
Waltking, A.E., and H. Zmachinski,Ibid. 54:454 (1977).
Waltking, A.E., and A.G. Goetz,CRC Crit. Rev. Food Sci Nutr. 19:99(1983).
Fore, S.P., L.A. Goldblatt and H.P. Dupuy,J. Am. Peanut Res. Educ. Assoc. 4:177 (1972).
Williams, J. L., and T.H. Applewhite,J. Am. Oil Chem. Soc. 54:461 (1977).
Selke, E., W.K. Rohweder and HJ. Dutton,Ibid.49:636 (1972).
Mordret, F., O. Morin and J.L. Coustille,Rev. Fr. Corp. Gras. 32:193(1985).
Jackson, H.W.,J. Am. Oil Chem. Soc. 58:227 (1981).
Warner, K. and E.N. Frankel,Ibid.62:100 (1985).
Selke, E., and E.N. Frankel,Ibid.64:749 (1987).
Van den Dool, H., and P.D. Kratz,J. Chromatogr. 11:463 (1963).
Jennings, W., and T. Shibamoto,Qualitative Analysis of Flavor and Fragrance Volatiles by Glass Capillary Gas Chromatography, Academic Press, New York, 1980, p. 472.
Hites, R.A., and K. Biemann,Anal. Chem. 42:855 (1970).
Mathews, R.F., R.A. Scanlon and L.M. Libbey,J. Am. Oil Chem. Soc. 48:745 (1971).
Badings, H.T.,Neth. Milk Dairy J. 14:236 (1970).
Badings, H.T.,J. Am. Oil Chem. Soc. 50:334 (1973).
Meijboom, P.W., and J.B.A. Stroink,Ibid.49:555 (1972).
Nakamura, K., I. Haruka and T. Tokunaga,Bull. Japan. Soc. Sci. Fish. 46:355(1980).
Stern, D.J., R.A. Flath, T.R. Mon, R. Teranishi, R.E. Lundin and M.E. Benson,J. Agric. Food Chem. 33:180 (1985).
deMan, J.M., F. Tie and L. deMan,J. Am. Oil Chem. Soc. 64:993 (1987).
Nawar, W.W., inFlavor Chemistry of Fats and Oils,edited by D.B. Min and T.H. Smouse, American Oil Chemists’ Society, Champaign, IL, 1985, p. 39.
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Presented at the AOCS meeting in New Orleans, LA in May 1987.
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Hsleh, T.C.Y., Williams, S.S., Vejaphan, W. et al. Characterization of volatile components of menhaden fish (brevoortia tyrannus) oil. J Am Oil Chem Soc 66, 114–117 (1989). https://doi.org/10.1007/BF02661797
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DOI: https://doi.org/10.1007/BF02661797