The diffusivity and solubility of oxygen in liquid tin and solid silver and the diffusivity

Abstract

The diffusivity and solubility of oxygen in liquid tin and solid silver in the temperature range of about 750° to 950°C (1023 to 1223 K) and the diffusivity of oxygen in solid nickel at 1393°C (1666 K) were determined using the electrochemical cell arrangement of cylindrical geometry: Liquid or Solid Metal + O (dissolved) ¦ ZrO₂ + (3 to 4%)CaO ¦ Pt, air The diffusivity and solubility of oxygen in liquid tin are given by:D _O(Sn) = 9.9 × 10⁻⁴ exp(−6300/RT) cm²/s (9.9 × 10⁻⁸ exp − 6300/RT m²/s) andN ^S_O (Sn) = 1.3 × 10⁵ exp(−30,000/RT) at. pct The diffusivity and solubility of oxygen in solid silver follow the relations:D _O(Ag) = 4.9 × 10⁻³ exp (−11,600/RT) cm²/s ( 4.9 × 10⁻⁷ exp − 11,600/RT m²/s) andN ^S_O (Ag) = 7.2 exp (−11,500/RT) at. pct The experimental value for the preexponential in the expression forD _O(Ag) is lower than the value calculated according to Zener’s theory of interstitial diffusion by a factor of 11. The diffusivity of oxygen in solid nickel at 1393°C (1666 K) was found to be 1.3 × 10⁻⁶ cm²/s (1.3 × 10⁻¹⁰ m²/s).