Skip to main content
SpringerLink
Log in

Factors which affect the stability of highly unsaturated fatty acids. II. The autoxidation of linoleic and alkali conjugated acid in the presence of metallic naphthenates

  • Published:
Journal of the American Oil Chemists’ Society

Summary

The addition of commercial paint driers to unconjugated linoleic acid increased the rate of diene conjugation during autoxidation and greatly lowered the amount of detectable peroxides. On the other hand, the addition of driers to the conjugated isomer lowered the amount of detectable peroxide but mildly promoted destruction of diene conjugation. The hydroperoxide decomposition role of driers is further supported. Metallic naphthenates increased the quantity of diene ketones in both unconjugated and conjugated acid though after a longer period of time in the latter case.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Riemenschneider, R. W., Trans. Am. Assoc. Cereal Chem.,5, 50 (1947).

    CAS  Google Scholar 

  2. Nicholson, D. G., and Holley, C. E., Ind. and Eng. Chem.,30, 114 (1938).

    Article  CAS  Google Scholar 

  3. Nicholson, D. G., Ind. and Eng. Chem.,31, 1300 (1939).

    Article  CAS  Google Scholar 

  4. Nicholson, D. G., Ind. and Eng. Chem.,34, 1175 (1942).

    Article  CAS  Google Scholar 

  5. Elm, A. C., Ind. and Eng. Chem.,26, 386 (1934).

    Article  CAS  Google Scholar 

  6. Stephens, H., Ind. and Eng. Chem.,24, 918 (1932).

    Article  CAS  Google Scholar 

  7. Gardner, W. H., and Waddell, R. B., Ind. and Eng. Chem.,33, 629 (1941).

    Article  CAS  Google Scholar 

  8. Yamada, T., Researches Electrotech. Lab. (Tokyo),443, 1–2 (1940); Chem. Zentr.,1, 3494 (1941); Chem. Abstracts,38, 2258 (1944).

    Google Scholar 

  9. Ivanov, K. I., Savinova, V. K., and Mikhailova, E. G., Physic. Chem. Jour. U.S.S.R.,12, 719 (1939).

    Google Scholar 

  10. Medvedev, S. S., Acta Physicochim. U.S.S.R.,9, 395 (1938).

    CAS  Google Scholar 

  11. Robertson, A., and Waters, W. A., Trans. Faraday Soc.,42, 201 (1946).

    Article  CAS  Google Scholar 

  12. Kummerow, F. A., and Green, E., J. Am. Oil Chemists’ Soc.,24, 196 (1947).

    Article  CAS  Google Scholar 

  13. Kummerow, F. A., Hite, J., and Kloxin, S., Poultry Sci.,27, 689 (1948).

    CAS  Google Scholar 

  14. Allen, R. R., Jackson, A., and Kummerow, F. A., J. Am. Oil Chem. Soc. (in press).

  15. Rollet, A., Z. Physiol. Chem.,62, 410 (1909).

    Google Scholar 

  16. Holman, R. T., and Elmer, O. C., J. Am. Oil Chem. Soc.,24 127 (1946).

    Article  Google Scholar 

  17. Von Mikusch, J. D., J. Am. Chem. Soc.,64, 1580 (1942).

    Article  Google Scholar 

  18. Wheeler, D. H., Oil and Soap,9, 89 (1932).

    Article  CAS  Google Scholar 

  19. Mitchell, J. H., Kraybill, H. R., and Zscheile, F. P., Ind. Eng. Chem. Anal. Ed.,15, 1 (1943).

    Article  CAS  Google Scholar 

  20. Lundberg, W. O., and Chipault, J. R., J. Am. Chem. Soc.,69, 833 (1947).

    Article  CAS  Google Scholar 

  21. Bolland, J. L., and Koch, H. P., Jour. Chem. Soc.,445 (1945).

  22. Mattiello, J. J., Protective and Decorative Coatings, Vol. I. John Wiley and Sons, Inc. (1941).

  23. Farmer, E. H., Trans. Faraday Soc.,42, 228, (1946).

    Article  CAS  Google Scholar 

  24. Hilditeh, T. P., Jour. Oil and Colour Chem. Assoc.,30, 1 (1947).

    Google Scholar 

Download references

Author information

Author notes

  1. A. H. Jackson

    Present address: Department of Biochemistry, Meharry Medical College, Nashville, Tennessee

Authors and Affiliations

  1. Kansas Agricultural Experiment Station, Manhattan, Kansas

    A. H. Jackson & F. A. Kummerow

Authors
  1. A. H. Jackson
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. F. A. Kummerow
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

The subject matter of this paper has been undertaken in cooperation with the office of Naval Research. The opinions or conclusions contained in this report are those of the authors. They are not to be construed as necessarily reflecting the views or indorsement of the Navy Department.

Portion of a thesis presented by A. H. Jackson as partial fulfillment of the requirements for the degree of Master of Science in Chemistry at Kansas State College.

Contribution No. 367, Department of Chemistry, Kansas State College.

About this article

Cite this article

Jackson, A.H., Kummerow, F.A. Factors which affect the stability of highly unsaturated fatty acids. II. The autoxidation of linoleic and alkali conjugated acid in the presence of metallic naphthenates. J Am Oil Chem Soc 26, 460–465 (1949). https://doi.org/10.1007/BF02651467

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02651467

Keywords

Search

Navigation