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Coarsening resistance of M2C carbides in secondary hardening steels: Part II. Alloy design aided by a thermochemical database

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Abstract

In high Co-Ni steels containing the strong carbide-forming elements Mo, Cr, and W, secondary hardening is accomplished by the precipitation of fine-scale M2C alloy carbides. Thermodynamic stability and coarsening resistance of these carbides depend on the alloy content of these elements. A model for the M2C coarsening kinetics in multicomponent alloys has been used to identify the optimum alloying addition for maximum coarsening resistance and as a basis for selection of four experimental alloy steels. Necessary information pertaining to the equilibrium in these steels was obtained using the Thermo-Calc software and database developed at the Royal Institute of Technology, Stockholm, Sweden.

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Lee, H.M., Allen, S.M. & Grujicic, M. Coarsening resistance of M2C carbides in secondary hardening steels: Part II. Alloy design aided by a thermochemical database. Metall Trans A 22, 2869–2876 (1991). https://doi.org/10.1007/BF02650248

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