Abstract
A quantitative study of the effect of various heat treatments on methyl ketone formation in butteroil was conducted. Methyl ketone formation was found to follow first-order reaction kinetics. The energy of activation was calculated to be approximately 26.55 kcal/mole. The ketones were formed in a fairly constant molar ratio approximating to the following C15,2∶C13,1∶C11,1∶C9,1∶C7,2∶C5,1. The temperature-time conditions had little or no effect on the ratio.
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Schwartz, D.P., Parks, O.W. & Yoncoskie, R.A. Quantitative studies on methyl ketone formation in butteroil: Effect of temperature. J Am Oil Chem Soc 43, 128–129 (1966). https://doi.org/10.1007/BF02646284
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DOI: https://doi.org/10.1007/BF02646284