Abstract
Single crystal samples of high-purity vanadium containing 95, 300, and 500 wt ppm oxygen were irradiated at 95°C in the Ames Laboratory Research Reactor to a dose of 1.4 x 1019 neutrons/cm2 (E > 1 MeV). The density and size distribution of radiation-produced defect clusters were analyzed by transmission electron microscopy in as-irradiated and post-irradiation-annealed material. The defect cluster density was observed to increase with increasing oxygen concentration and the average defect cluster size to decrease. Upon post-irradiation annealing the density decreased and the average size increased, but higher annealing temperatures were required for higher oxygen material. The results are discussed in terms of the nucleation of defect clusters at oxygen atoms and small oxygen-atom aggregates. The increased stability against annealing of higher oxygen vanadium is believed to be due to the greater segregation of oxygen at the defect clusters.
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References
M. Wilkens: inVacancies and Interstitials in Metals, A. Seegeret al, eds., North-Holland Publishing Co., Amsterdam, 1970.
M. R. Rühle: inRadiation-Induced Voids in Metals, J. W. Corbett and L. C. Ianniello, eds., U.S. Atomic Energy Commission, Washington, D.C., 1972.
Effect of Radiation on Substructure and Mechanical Properties of Metals and Alloys, J. Moteff, ed., Special Technical Publication 529, ASTM, Philadelphia, 1973.
The Nature of Small Defect Clusters, M. J. Makin, ed., vols. I and II, AERE-R 5269, H. M. Stationery Office, London, 1966.
Defects and Defect Clusters in B.C.C. Metals and Their Alloys, R. J. Arsenault. ed.,Nuclear Metallurgy, vol. 18, National Bureau of Standards, Gaithersburg, Md., 1973.
Defects in Refractory Metals, R. de Batist, J. Nihoul, and L. Stals, eds., SCK/CEN, Mol, Belgium, 1972.
S. A. Bradford and O. N. Carlson:Trans. ASM, 1962, vol. 55, p. 169.
Fusion Reactor First Wall Materials, L. C. Ianniello, ed., WASH-1206, U.S. Atomic Energy Commission, Washington, D.C., 1972.
J. D. Elen: Report RCN-96,Reactor Cent. Ned., Petten, December 1967.
R. C. Rau and R. L. Ladd:J. Nucl. Mater, 1969, vol. 33, p. 297.
F. A. Smidt:Radiat. Effects, 1971, vol. 10, p. 205.
K. Shiraishi, K. Fukaya, and Y. Katano:J. Nucl. Mater., 1972, vol. 44, p. 228.
M. Bocek and J. D. Elen:J. Nucl. Mater., 1972, vol. 44, p. 194.
K. Shiraishi, K. Fukaya, and Y. Katano:J. Nucl. Mater, 1974, vol. 54, p. 275.
M. Eto, K. Fukaya. and K. Shiraishi:J. Nucl. Mater., 1973, vol. 48, p. 365.
V. A. Fassel, W. E. Dallmann, R. Skogerboe, and V. M. Horrigan:Anal. Chem., 1962. vol. 34, p. 1364.
Book of ASTM Stand., part 31, p. 30, Amer. Soc. Test. Mater., Philadelphia, 1966.
P. B. Hirsch, A. Howie, R. B. Nicholson, D. W. Pashley, and M. J. Whelan:Electron Microscopy of Thin Crystals, Butterworths, London, 1965.
R. Bajaj: Ph.D. Thesis, Iowa State University, Ames, Iowa, 1975.
M. Eto, Y. Matsuo, S. Ishino, and Y. Mishima:J. Nucl. Mater., 1974, vol. 52, p. 309.
R. W. Powers and M. V. Doyle:J. Appl. Phys., 1959, vol. 30, p. 514.
F. A. Schmidt and J. C. Warner:J. Less-Common Metals, 1972, vol. 26, p. 325.
R. P. Tucker and M. S. Wechsler:Radial. Effects, 1970, vol. 3, p. 73.
R. P. Tucker, S. M. Ohr, and M. S. Wechsler: inRadiation Damage in Reactor Materials, vol. 1, p. 215, International Atomic Energy Agency, Vienna, 1969.
S. M. Ohr, R. P. Tucker, and M. S. Wechsler:Trans. Jap. Inst. Metals Suppl., 1968, vol. 9, p. 187.
B. A. Loomis and S. B. Gerber.Acta Met., 1973. vol. 21, p. 165.
M. Wilkens: inVacancies and Interstitials in Metals, A. Seegeret al, eds., p. 485, North-Holland Publishing Co., Amsterdam, 1970.
J. F. Mcllwain, C. W. Chen, R. Bajaj, and M. S. Wechsler: inEffects of Radiation on Substructure and Mechanical Properties of Metals and Alloys, Special Technical Publication 529, Amer. Soc. Test. Mater., Philadelphia, 1973, p. 529.
J. T. Stanley, J. M. Williams, W. E. Brundage, and M. S. Wechsler:Acta Met., 1972, vol. 20, p. 191.
J. M. Williams, W. E. Brundage, and J. T. Stanley:Metal. Sci. J., 1968, vol. 2, p. 100.
A. A. Johnson:Scr. Met., 1973, vol. 7, p. 1.
A. A. Johnson:Scr. Met., 1973, vol. 7, p. 15.
M. S. Wechsler, J. M. Williams, and J. T. Stanley:Scr. Met., 1973, vol. 7, p. 7.
B. S. Brown, T. H. Blewitt, T. L. Scott, and A. C. Klank:J. Nucl. Mater., 1974, vol. 52, p. 215.
M. S. Wechsler, D. G. Alexander, R. Bajaj, and O. N. Carlson:Nuclear Metallurgy, vol. 18, p. 127, National Bureau of Standards, Gaithersburg, Md., 1973.
D. F. Hasson and R. J. Arsenault:Radiat. Effects, 1974, vol. 21, p. 203.
R. J. Arsenault and E. Pink:Mater. Sci. Eng., 1971, vol. 8, p. 141.
M. S. Wechsler: inDefects in Refractory Metals, R. de Batistet al, eds., p. 235, SCK/CEN, Mol, Belgium, 1972.
M. J. Makin and F. G. Minter:Acta Met., 1959, vol. 7, p. 361.
S. M. Ohr, M. S. Wechsler, C. W. Chen, and N. E. Hinkle: inSecond International Conference on Strength of Metals and Alloys, p. 742, ASM, Metals Park, Ohio, 1970.
S. M. Ohr, R. P. Tucker, and M. S. Wechsler:Phys. Status Solidi, 1970, vol. A2, p. 559.
J. Venetch, A. A. Johnson, and K. Mukherjee:J. Nucl. Mater., 1970, vol. 34, p. 343.
G. R. Smolik and C. W. Chen:J. Nucl. Mater., 1970, vol. 35, p. 94.
D. F. Hasson:Nuclear Metallurgy, vol. 18, p. 147, National Bureau of Standards, Gaithersburg, Md., 1973.
M. S. Wechsler and R. Bajaj:Scr. Met., 1974, vol. 8, p. 885.
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The work was performed at Ames Laboratory under contract with Energy Research and Development Administration.
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Bajaj, R., Wechsler, M.S. Defect clusters in neutron-irradiated vanadium containing oxygen. Metall Trans A 7, 351–358 (1976). https://doi.org/10.1007/BF02642830
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DOI: https://doi.org/10.1007/BF02642830