Skip to main content
Log in

The thermodynamic properties of dilute solutions of oxygen in the liquid Fe-Ni-Co alloys

  • Published:
Metallurgical Transactions Aims and scope Submit manuscript

Abstract

Thermodynamic properties of dilute solutions of oxygen in the system Fe-Ni-Co have been studied by means of the hydrogen-water vapor equilibrium. Evidence is presented which shows Henry’s Law is obeyed by oxygen within experimental error over a substantial composition range. The standard Gibbs energy of solution of oxygen surface is presented for the entire system at 1550°C. Equations are presented which show the variation of the standard Gibbs energy of solution of oxygen as a function of temperature for five compositions of equal Ni-Co ratio.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. F. Elliott, M. Gleiser, and V. Ramakrishna:Thermochemistry for Steel-making, Vol. II, Addison Wesley Publishing Co., 1963.

  2. C. Wagner:Thermodynamics of Alloys, Addison Wesley Press, Inc., Cambridge, 1952.

    Google Scholar 

  3. E. S. Tankins: unpublished Data, NAVAIRDEVCEN, Johnsville, Pa., 1966.

  4. E. S. Tankins, N. A. Gokcen, and G. R. Belton:Trans. TMS-AIME, 1964, vol. 230, pp. 820–26.

    CAS  Google Scholar 

  5. N. A. Gokcen:Trans. TMS-AIME, 1958, vol. 212, pp. 93–100.

    CAS  Google Scholar 

  6. Janaf Thermodynamic Tables: The Dow Chemical Co., Midland, Mich., 1961.

  7. G. R. Belton and R. J. Fruehan:J. Phys. Chem., 1969, vol. 71, pp. 1403–09.

    Article  Google Scholar 

  8. R. G. Blossey and R. D. Pehlke:Trans. TMS-AIME, 1966, vol. 236, pp. 566–69.

    CAS  Google Scholar 

  9. C. H. P. Lupis and J. F. Elliott:Acta Met., 1966, vol. 14, pp. 529–38.

    Article  CAS  Google Scholar 

  10. C. H. P. Lupis and J. F. Elliott:Trans. TMS-AIME, 1965, vol. 233, pp. 829–38.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tankins, E.S. The thermodynamic properties of dilute solutions of oxygen in the liquid Fe-Ni-Co alloys. Metall Trans 1, 1897–1904 (1970). https://doi.org/10.1007/BF02642789

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02642789

Keywords

Navigation