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Some recent developments in the homogeneous catalyzed hydrogenation of olefins

  • Technical
  • Symposium: Hydorogenation Conducted by American Oil Chemists’ Society at the AOCS 61st Annual Meeting, New Orleans, La. April 26–30, 1970
  • Published:
Journal of the American Oil Chemists Society

Abstract

It has been found that the amount of double bond isomerization accompanying homogeneous olefin hydrogenations over tris (triphenylphosphinechlororhodium is markedly influenced both by the duration of hydrogen presaturation of the catalyst and the presence of oxygen in the reaction mixture. These results are compared to those obtained over a heterogeneous catalyst, 5% rhodium on chareoal.

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Authors and Affiliations

  1. Chemistry Department, Seton Hall University, 07079, South Orange, N.J.

    Robert L. Augustine & Jan F. Van Peppen

Authors
  1. Robert L. Augustine
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  2. Jan F. Van Peppen
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Augustine, R.L., Van Peppen, J.F. Some recent developments in the homogeneous catalyzed hydrogenation of olefins. J Am Oil Chem Soc 47, 478–481 (1970). https://doi.org/10.1007/BF02639231

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  • DOI: https://doi.org/10.1007/BF02639231

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