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Hydrogen-bonding. Part 22. Characterization of soybean oil and prediction of activity coefficients in soybean oil from inverse gas chromatographic data

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Journal of the American Oil Chemists Society

Abstract

Previously reported results on twenty-two gaseous compounds with soybean oil as the stationary gas chromatographic phase have been used to characterize soybean oil in terms of dipolarity/polarizability, hydrogen-bond basicity and lipophilicity. The solubility of these gases in soybean oil has been factored into components that show exactly the compound-soybean oil interactions that favor solubility. The same equation used to obtain this information also can be used to predict the gas chromatographic specific retention volume and then the weight-fraction activity coefficient for numerous other compounds on soybean oil, thus leading to predictions of the solubility behavior of these compounds as bulk liquids with soybean oil.

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References

  1. King, J.W., and G. List,J. Am. Oil Chem. Soc. 67:424 (1990).

    CAS  Google Scholar 

  2. Romdhane, I.H., and R.P. Danner,J. Chem. Eng. Data 36:15 (1991).

    Article  CAS  Google Scholar 

  3. Abraham, M.H., G.S. Whiting, R.M. Doherty and W.J. Shuely,J. Chromatogr. 587:213 (1991).

    Article  CAS  Google Scholar 

  4. Abraham, M.H., G.S. Whiting, R.M. Doherty and W.J. Shuely, Ibid.:229 (1991).

    Article  CAS  Google Scholar 

  5. Abraham, M.H., I. Hamerton, J.B. Rose and J.W. Grate,J. Chem. Soc. Perkin Trans. 2:1417 (1991).

    Google Scholar 

  6. Abraham, M.H., G.S. Whiting, R.M. Doherty and W.J. Shuely, Ibid.:1451 (1990).

    Google Scholar 

  7. Abraham, M.H., P.L. Grellier and R.A. McGill, Ibid.:523 (1988).

    Google Scholar 

  8. Abraham, M.H., G.S. Whiting, R.M. Doherty and W.J. Shuely,J. Chromatogr. 518:329 (1990).

    Article  CAS  Google Scholar 

  9. Abraham, M.H., and G.S. Whiting, Ibid.:229 (1992).

    Article  CAS  Google Scholar 

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Abraham, M.H., Whiting, G.S. Hydrogen-bonding. Part 22. Characterization of soybean oil and prediction of activity coefficients in soybean oil from inverse gas chromatographic data. J Am Oil Chem Soc 69, 1236–1238 (1992). https://doi.org/10.1007/BF02637688

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  • DOI: https://doi.org/10.1007/BF02637688

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