Skip to main content
Log in

Comparison of fatty acid esters of sucrose and of polyoxyethylene in built detergent compositions

  • Technical
  • Published:
Journal of the American Oil Chemists Society

Abstract

The addition of suerose monotallowate to an aqueous solution of alkanolamine alkylaryl sulfonate lowers the total active-agent content required for the formation of liquid crystals. In contrast, the addition of polyoxyethylene esters of fatty acids to the alkylaryl sulfonate solution increased the total amount of active agent required for the formation of liquid crystals. The deaggregating effect of the ethylene oxide-derived nonionies was reflected in reduced foam and detergeney for combinations of these nonionics and alkylaryl sulfonate. Foam and detergeney remained at a high level with combinations of sucrose monotallowate and alkylaryl sulfonate. Higher hydrophile-lipophile balance (HLB) values were obtained with the sugar esters than with the polyoxyethylene nonionics. The results were examined in terms of Winsor’s theory of intermicellar equilibria.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Brown, A.G., Thuman, W.C., and McBain, J.W., J. Colloid Sci.,8, 491 (1953).

    Article  CAS  Google Scholar 

  2. Epstein, M.B., Ross, J., and Jakob, C.W., J. Colloid Sci.,9, 50 (1954).

    Article  CAS  Google Scholar 

  3. Shick, M.J., and Fowkes, F.M., J. Phys. Chem.,61, 1062 (1957).

    Article  Google Scholar 

  4. Ross, S., and Bramfitt T.H., J. Phys. Chem.,61, 1261 (1957).

    Article  CAS  Google Scholar 

  5. Lawrence, A.S.C., Nature,183, 1491 (1959).

    Article  ADS  CAS  Google Scholar 

  6. Osipow, L.I., Snell, F.D., Marra, D., York, W.C., and Finchler, A., Ind. Eng. Chem.,48, 1459 (1956).

    Article  CAS  Google Scholar 

  7. ASTMD 1173-53.

  8. Bulletin SE-1 I, Sucro-Chemical Division, Colonial Sugars Company, Gramerey, La., Aug. 31, 1960.

  9. Griffin, W.C., J. Soc., Cosmetic Chemists,1, 311 (1949).

    Google Scholar 

  10. Davies, J.T., Proceedings Second Int. Cong. Surface Activity, Vol. 1, CT409, London, Butterworths, 1957.

    Google Scholar 

  11. Griffins, W.C., J. Soc. Cosmetic Chemists,5, 249 (1954).

    Google Scholar 

  12. Winsor, P.A., Chemistry and Industry, June 4, 1960, p. 645.

Download references

Author information

Authors and Affiliations

Authors

Additional information

Presented before the 34th fall meeting, American Oil Chemists’ Society, October 17–19, 1960, New York.

About this article

Cite this article

Osipow, L.I., Snell, F.D. Comparison of fatty acid esters of sucrose and of polyoxyethylene in built detergent compositions. J Am Oil Chem Soc 38, 184–189 (1961). https://doi.org/10.1007/BF02633227

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02633227

Keywords

Navigation