Abstract
Fats and fatty acids are polymerized by oxidative or thermal processes. Structures have been deduced by using a number of chemical and physical techniques. General methods applicable to the analysis of polymerized oils include determinations of acetone number, iodine value (I.V.), molecular weight, dielectric constant, viscosity, and refractive index. Monomers, dimers, and trimers are separated generally by molecular distillation. In addition, urea fractionation and a number of chromatographic techniques are useful for the detection of monomers, dimers, and polymers.
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References
Newman, A. A., Food Manuf. (London),33, 374; 422 (1958).
Perkins, E. G., Food Technol.,14, 508 (1960).
Sonntag, N. O. V., in “Fatty Acids, Their Chemistry Properties and Uses,” editor, K. S. Markley, Interscience Publishers, New York, N. Y., Part 2, 1961, p. 1043.
Privett, O. S., JAOCS,36, 507 (1959).
Bradley, T. F., and H. F. Pfann, Ind. Eng. Chem.,32, 694 (1940).
Bradley, T. F., and W. B. Johnston,Ibid., 32, 802 (1940).
Bradley, T. F., and W. B. Johnston,Ibid. 33, 86 (1941).
Paschke, R. F., and D. H. Wheeler, JAOCS,26, 278 (1949).
Paschke, R. F., J. E. Jackson, and D. H. Wheeler, Ind. Eng. Chem.,44, 1113 (1952).
Chin, C., J. Chem. Soc. Japan,53, 281 (1950).
Clingman, A. L., D. E. A. Rivett, and D. A. Sutton, J. Chem. Soc. (London), 1088 (1954).
Waterman, H. I., J. P. Cordia, and B. Pennekamp, Research (London),2, 483 (1949).
Waterman, H. I., C. J. Kips, and J. Van Steenis,Ibid. (London),4, 96 (1951).
Boelhouwer, C., and H. L. Waterman,Ibid., (London),4, 245 (1951).
Boelhouwer, C., A. C. Hol, and H. I. Waterman,Ibid. (London),5, 336 (1953).
Boelhouwer, C., L. T. Tien, and H. I. Waterman,Ibid.,, (London),6, 55 S (1953).
Sutherland, E., J. Oil Colour Chemists' Assoc.,28, 137 (1945).
Norton, K. B., D. E. A. Rivett, and D. A. Sutton, Chem. and Ind. (London), 1452 (1961).
Mehta, T. N., and S. A. Sharma, JAOCS,34, 448 (1957).
Rossman, E., Fettchem. Umschan,40, 117 (1933).
Paschke, R. F., and D. H. Wheeler, JAOCS,32, 473 (1955).
Rivett, D. E. A.,Ibid., 33, 635 (1956).
MacDonald, J. A.,Ibid.,,33, 394 (1956).
McInnes, A. G., E. P. Cooper, and J. A. MacDonald, Can. J. Chem.,39, 1906 (1961).
Cristol, S. J., and N. L. Hause, J. Am. Chem. Soc.,74, 2193 (1952).
Holman, R. T., in “Progress in the Chemistry of Fats and Other Lipids,” Academic Press, New York, N.Y., Vol. II, 1954, p. 51.
Chang, S. S., and F. A. Kummerow, JAOCS,30, 403 (1953).
Williamson, L., J. Appl. Chem. (London),3, 301 (1953).
Frankel, E. N., C. D. Evans, and J. C. Cowan, JAOCS,37, 418 (1960).
Perkins, E. G., and F. A. Kummerow,Ibid.,,36, 371 (1959).
Firestone, D., W. Horwitz, L. Friedman, and G. M. Shue,Ibid.,,38, 253 (1961).
Mehlenbacher, V. C., “The Analysis of Fats and Oils,” The Garrard Press, Champaign, Illinois, 1960.
Link, W. E., JAOCS,36, 477 (1959).
O'Hare, G. A., P. S. Hess, and A. F. Kopacki,Ibid.,,26, 484 (1949).
Täufel, K., Cl, Franzke, and H. Hoppe Deut. Lebensm. Rundschau,54, 245 (1958).
Sims, R. P. A., JAOCS,34, 466 (1957).
Sims, R. P. A. Ind. Eng. Chem.,47, 1049 (1955).
Flory, P. J., J. Am Chem. Soc.,62, 1057 (1940).
Bernstein, I. M., J. Phys. and Colloid Chem.,52, 613 (1948).
Paschke, R. F., and D. H. Wheeler, JAOCS,31, 208 (1954).
Walker, F. T., T. Mackay, and K. B. Taylor, J. Oil and Colour Chemists' Assoc.,36, 667 (1953).
Lück, H., E. Rickerl, and A. Pavlik, Fette, Seifen, Anstrichmittel,64, 239 (1962).
Donnelly, T. H., J. Phys. Chem.,64, 1830 (1960).
McQuillen, T., and F. N. Woodward, J. Oil and Colour Chemists' Assoc.,23, 8 (1940).
Privett, O. S., W. D. McFarlane, and J. H. Gass, JAOCS,24, 204 (1947).
Mehta, T. N., and S. A. Sharma,Ibid., 33, 38 (1956).
Bernstein, I. M., J. Oil and Colour Chemists' Assoc.,32, 447 (1949).
Kaufmann, H. P., J. Budwig, and C. W. Schmidt, Fette u. Seifen,53, 408 (1951).
Deutschen Gesellschaft für Fettwissenschaft e.V. (DGF), Münster, Westf., Germany, 1950, Method C.VI (53).
AOCS, “Official and Tentative Methods,” 2nd ed., rev. to 1961. Chicago, 1946–61, Method Ka 11-55.
Langmuir, I., Phys. Rev.30, 201 (1927).
Burrows G., “Molecular Distillation,” Oxford University Press, London, 1960.
Weissberger, A., “Technique of Organic Chemistry, Vol. IV, Distillation,” Interscience Publishers, Inc., New York, 1951.
Carney, T. D., “Laboratory Fractional Distillation,” The MacMillan Co., New York, 1949.
Hickman, K., Anal. Chem.,21, 638 (1949).
Rushman, D. F., and E. M. G. Simpson, J. Oil and Colour Chemists' Assoc.,37, 319 (1954).
Booy, H., and H. I. Waterman, Anal. Chim. Acta,3, 440 (1949).
Sims, R. P. A., Vacuum,2, 245 (1954).
Paschke, R. F., J. R. Kerns, and D. H. Wheeler, JAOCS,31, 5 (1954).
Cowan, J. C., L. B. Falkenberg, and H. M. Teeter, Anal. Ed., Ind. Eng. Chem.,16, 90 (1944).
Crampton, E. W., R. H. Common, F. A. Farmer, A. F. Wells, and D. Crawford, J. Nutrition,49, 333 (1953).
Wells, A. F., and R. H. Common, J. Sci. Food Agri.,4, 233 (1953).
Firestone, D., S. Nesheim, and W. Hurwitz, J. Assoc. Offic. Agric. Chemists,44, 465 (1961).
Frankel, E. N., C. D. Evans, H. A. Moser, D. G. McConnell, and J. C. Cowan, JAOCS,38, 130 (1961).
Rost, H. E., Fette, Seifen, Anstrichmittel,64, 427 (1962).
Kaufmann, H. P., and W. H. Nitsch,Ibid., 56, 154 (1954).
Mangold, H. K., JAOCS,38, 708 (1961).
Nesheim, S. unpublished experiments, 1961.
Vandem Heuvel, W. J. A., C. C. Sweeley, and E. C. Horning, J. Am. Chem. Soc.,32, 3481 (1960).
Huebner, V. R., JAOCS,38, 628 (1961).
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Firestone, D. The determination of polymers in fats and oils. J Am Oil Chem Soc 40, 247–255 (1963). https://doi.org/10.1007/BF02632670
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DOI: https://doi.org/10.1007/BF02632670