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Reactions of azelaaldehydic esters

  • Technical
  • Symposium: Detergents II The Next Phase: Textiles And Detergents Of The ′70’S
  • Published:
Journal of the American Oil Chemists’ Society

Abstract

Alkyl azelaaldehydates and their acetals can undergo reactions at either the aldehyde or the ester group to form a variety of novel and reactive monomers and polymers. Pertinent reactions of the aldehyde group (and resultant products) include acetalization with pentaerythritol (diester-acetal), acetalization with glycerol (hydroxy ester-acetal), hydrogenation (hydroxy ester), reductive alkylation of ammonia (amino acid and imino diester), aldolization (dibasic acid) and hydrazone formation (azine dibasic acids). Reactions at the ester group include aminolysis (diacid amides) and hydrazinolysis (hydrazide acetal). These various products can undergo self-condensation or condensation with glycols or diamines to form polyesters, polyamides, poly (ester-acetals) and poly (amideacetals). Polymers with cyclic acetal structures in the polymer backbone have latent crosslinking capabilities.

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Authors and Affiliations

  1. Northern Regional Research Laboratory, 61604, Peoria, Illinois

    E. H. Pryde & J. C. Cowan

Authors
  1. E. H. Pryde
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  2. J. C. Cowan
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Additional information

No. Utiliz. Res. Dev. Div., ARS, USDA.

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Pryde, E.H., Cowan, J.C. Reactions of azelaaldehydic esters. J Am Oil Chem Soc 46, 213–218 (1969). https://doi.org/10.1007/BF02632508

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  • DOI: https://doi.org/10.1007/BF02632508

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