Summary
An inert diluent, molecularly distilled mineral oil, when present in 90% concentration, permitted, in linseed oil, the polymerization of acyl groups in the absence of inter-glyceride reaction. Comparison of the data for the polymerization of linseed oil in 10, 20, and 100% concentrations showed a marked concentration dependence for the following: polymerization of acyl groups and glyceride molecules; change in specific refraction and the ratio of percentages by weight polymeric acyl groups to polymeric glyceride molecules.
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References
Boelhouwer, C., Jol, C., and Waterman, H. I., Research,5, 336–338 (1952).
Paschke, R. F., Jackson, J. E., and Wheeler, D. H., Ind. Eng. Chem.,44, 1113–1118 (1952).
Sims, R. P. A., Vacuum2, 245–256 (1952).
Sims, R. P. A., J. Am. Oil Chemists’ Soc.,31, 144–147 (1954).
Sims, R. P. A., (submitted to J. Am. Oil Chemists’ Soc.).
Vlugter, J. C., Waterman, H. I., and Van Westen, H. A., J. Inst. Petrol. Tech.,18, 735–750 (1932).
Waterman, H. I., Cordia, J. P., and Pennekampf, B., Research,2, 483 (1949).
Wiseblatt, L., Wells, A. F., and Common, R. H., J. Sci. Food and Agr.,4, 227–233 (1953).
Zuckerman, A., Sims, R. P. A., and Grace, N. H., Can. J. Tech.,32, 10–16 (1954).
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N.R.C. No. 3322.
Part of this paper was presented at the Protective Coatings Section, Chemical Institute of Canada, Montreal, June, 1952.
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Sims, R.P.A. Dilution polymerization of linseed oil. J Am Oil Chem Soc 31, 327–331 (1954). https://doi.org/10.1007/BF02632162
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DOI: https://doi.org/10.1007/BF02632162