Summary
Citric and ascorbic acids delayed substantially the rate of peroxide accumulation, during the induction period, of lard which contained pro-oxidant levels ofα-tocopherol or NDGA. While low levels (.025%) of both acids showed effective synergistic action withα-tocopherol, higher levels were proportionately less effective.
Tocopherol had a marked protective effect on ascorbic and phosphoric acids in autoxidizing lard.
Evidence indicates that ascorbic and citric acid function as synergists in natural fats and oils by inhibiting the antioxidant catalysis of peroxide decomposition. This concept is discussed in relation to current theories of the mechanism of synergist action.
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Journal Paper No. 742 of the Purdue University Agricultural Experiment Station, Lafayette, Ind.
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Privett, O.S., Quackenbush, F.W. The relation of synergist to antioxidant in fats. J Am Oil Chem Soc 31, 321–323 (1954). https://doi.org/10.1007/BF02632160
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DOI: https://doi.org/10.1007/BF02632160