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Reactions of polyunsaturated fatty alcohols. IX. Molecular-weight distribution of some conjugated soybean vinyl ether homopolymers

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Journal of the American Oil Chemists Society

Abstract

The molecular-weight distributions of several conjugated soybean vinyl ether homopolymers were studied by means of the integral fractionation technique. Polymers having number average molecular weights of 2,200, 4,800 and 10,000 prepared with stannic chloride as catalyst as well as a polymer having a molecular weight of 3,400 prepared with boron trifluoride as catalyst were included in the study. The observed distributions for all the polymers were found to approximate the socalled “most probable” distributions expected theoretically for polymers obtained by simple difunctional polymerization.

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References

  1. Boyer, R. F., J. Polymer Sci.,8, 73–90 (1952).

    Article  CAS  Google Scholar 

  2. Boyer, R. F.,ibid.,,9, 197–218 (1952).

    Article  CAS  Google Scholar 

  3. Dufek, E. J., Awl, R. A., Gast, L. E., Cowan, J. C., and Tecter, H. M., J. Am. Oil Chemists' Soc.,37, 37–40 (1960).

    CAS  Google Scholar 

  4. Flory, P. J., “Principles of Polymer Chemistry,” Ithaca, N. Y., Cornell University Press, 1953, p. 320.

    Google Scholar 

  5. Flory, P. J.,Ibid., “, pp. 353, 370.

    Google Scholar 

  6. Flory, P. J.,ibid., “, pp. 217–224.

    Google Scholar 

  7. Gast, L. E., Schneider, W. J., and Teeter, H. M., J. Am. Oil Chemists's Soc.,34, 307–310 (1957).

    CAS  Google Scholar 

  8. Mustakas, G. C., Raether, M. C., and Griffin, E. L., Jr.,ibid.,,37, 100–103 (1960).

    CAS  Google Scholar 

  9. Schneider, W. J., Gast, L. E., Melvin, E. H., Glass, C. A., and Teeter, H. M.,Ibid., 34, 244–247 (1957).

    CAS  Google Scholar 

  10. Spencer, R. S., J. Polymer Sci.,3, 606–607 (1948).

    Article  CAS  Google Scholar 

  11. Teeter, H. M., Dufek, E. J., Coleman, C. B., Glass, C. A., Melvin, E. H., and Cowan, J. C., J. Am. Oil Chemists' Soc.,33, 399–404 (1956).

    CAS  Google Scholar 

  12. Teeter, H. M., Gast, L. E., and Cowan, J. C., Ind. Eng. Chem.,50, 1703–1704 (1958).

    Article  CAS  Google Scholar 

  13. Unpublished data, Northern Regional Research Laboratory.

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This is a laboratory of the Northern Utilization Research and Development Division, Agricultural Research Service, U. S. Department of Agriculture.

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Teeter, H.M., Dorman, L.C. & Harris, L. Reactions of polyunsaturated fatty alcohols. IX. Molecular-weight distribution of some conjugated soybean vinyl ether homopolymers. J Am Oil Chem Soc 37, 552–555 (1960). https://doi.org/10.1007/BF02631595

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  • DOI: https://doi.org/10.1007/BF02631595

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