Summary
A number of vinyl ethers of C18 fatty alcohols have been prepared by reaction of the alcohol with acetylene at atmospheric pressure in the presence of a basic catalyst. Infrared spectroscopic data on long-chain fatty alcohols, their vinyl ethers, and related chemical derivatives have been obtained. Methods of analysis of long-chain vinyl ethers for vinyl group have been developed, namely, iodometric, hydroxylamine, and infrared methods.
Preliminary experiments on the polymerization of long-chain vinyl ethers with ionic catalysts were carried out.
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Teeter, H.M., Dufek, E.J., Coleman, C.B. et al. Reactions of unsaturated fatty alcohols. I. Preparation and properties of some vinyl ethers. J Am Oil Chem Soc 33, 399–404 (1956). https://doi.org/10.1007/BF02630766
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DOI: https://doi.org/10.1007/BF02630766