Skip to main content
SpringerLink
Log in

Autoxidation of fatty acid esters in the presence of a heavy metal catalyst “Salcomine” (Co[II]-bissalicylalethylenedi-imine): II. Formation of a reaction product from a peroxy radical and salcomine

  • Published:
Lipids

Abstract

The formation of ionic Co(II)-bis-salicylalaethylenedi-imine complexes of peroxy radicals of methyl esters of fatty acids was followed by means of UV spectra. Typical compounds were isolated and purified, and analyzed for Co content. IR spectra were determined. The mechanism of the autoxidation of fatty acid methyl esters in the presence of “Salcomine” (Co[II]-bissalicylalethylene-di-imine) has been outlined, and its effect is explained as an oxidative addition reaction, resulting from coordinative unsaturation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Jarvi, P.K., In press.

  2. Heaton, P.W., and N. Uri, J. Lipid Res. 2:152 (1961).

    PubMed  CAS  Google Scholar 

  3. Ingold, K.U., “Lipids and Their Oxidation,” Edited by H.W. Shulz, Avi Publishing Co., London, 1962, p. 93.

    Google Scholar 

  4. Subbarao, R., M.W. Roomi, M.R. Subbarao and K.T. Achaya, J. Chromatogr. 9:295 (1962).

    Article  PubMed  CAS  Google Scholar 

  5. Bellamy, L.J., “The Infrared Spectra of Complex Molecules,” Methuen and Co. Ltd., London, 1962, p. 145.

    Google Scholar 

  6. Bellamy, L.J., and R.F. Branch, J. Chem. Soc. 1954:4491.

  7. Lecomte, J., Discussions Faraday Soc. 9:125 (1950).

    Article  Google Scholar 

  8. Khan, N.A., W.E. Tolberg, D.H. Wheeler and W.O. Lundberg, JAOCS 31:460 (1954).

    CAS  Google Scholar 

  9. Collmann, J.P., Accounts of Chem. Res. 1:136 (1968).

    Article  Google Scholar 

  10. Girard, T.A., and M. Beisbiel, JAOCS 42:828 (1956).

    Google Scholar 

  11. Marcuse, R., Ibid. 39:97 (1962).

    CAS  Google Scholar 

  12. Pekkarinen, L., and P. Rissanen, Suomem Kemistilehti 39B:50 (1966).

    Google Scholar 

  13. Pekkarinen L., and E. Porkka, Ibid. 40B:54 (1967).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. University of Helsinki, Helsinki, Finland

    Pentti K. Jarvi

  2. The Hormel Institute, University of Minnesota, 55912, Austin, Minnesota

    Pentti K. Jarvi

Authors
  1. Pentti K. Jarvi
    View author publications

    You can also search for this author in PubMed Google Scholar

About this article

Cite this article

Jarvi, P.K. Autoxidation of fatty acid esters in the presence of a heavy metal catalyst “Salcomine” (Co[II]-bissalicylalethylenedi-imine): II. Formation of a reaction product from a peroxy radical and salcomine. Lipids 7, 788–792 (1972). https://doi.org/10.1007/BF02533247

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02533247

Keywords

Search

Navigation