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Electromigration of Bk(IV) and some other tetravalent cations in nitric acid solutions

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Abstract

Electromigration of Bk(IV) and Ce(IV) in mixed HNO3−HClO4 solutions at constant total acid concentration of 6M has been investigated. Comparative electromigration of Bk(IV), Pu(IV), Th(IV) and Ce(IV) has been studied in nitric acid solutions at concentrations from 2M to 16M. Comparison of the obtained values of mobility shows that the ability to form negatively charged hexanitrato complexes in nitric acid solutions decreases with a decrease in ionic radius of the cations: Ce(IV), Th(IV), Pu(IV), Bk(IV). The mobility corresponding to negatively charged ions in the case of Bk(IV) appears only at HNO3 concentrations higher than 10M. This fact allowed to explain the specific features of ion-exchange and solvent extraction behaviour of Bk(IV).

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References

  1. F. L. MOORE, Anal. Chem., 39 (1967) 1874.

    Article  CAS  Google Scholar 

  2. F. L. MOORE, Anal. Chem., 41 (1969) 1658.

    Article  CAS  Google Scholar 

  3. A. J. SHAFIYEV, Y. V. YEFREMOV, Radiokhimiya, 14 (1972) 735.

    Google Scholar 

  4. V. N. KOSYAKOV, N. G. YAKOVLEV, G. M. KASAKOVA, E. A. YERIN, V. V. KOPYTOV, Radiokhimiya, 19 (1977) 486.

    CAS  Google Scholar 

  5. G. A. SIMAKIN, V. N. KOSYAKOV, A. A. BARANOV, E. A. YERIN, V. V. KOPYTOV, G. A. TIMOFEYEV, Radiokhimiya, 19 (1977) 336.

    Google Scholar 

  6. A. A. BARANOV, G. A. SIMAKIN, E. A. YERIN, V. N. KOSYAKOV, G. A. TIMOFEYEV, A. G. RYKOV, Radiokhimija, 21 (1979) 59.

    CAS  Google Scholar 

  7. A. D. JONES, G. R. CHOPPIN, Actinide Reviews, 1 (1969) 311.

    CAS  Google Scholar 

  8. J. L. RYAN, J. Phys. Chem., 64 (1960) 1375.

    CAS  Google Scholar 

  9. H. A. McKAY, J. L. WOODHEAD, J. Chem. Soc., 2 (1960) 717.

    Google Scholar 

  10. A. S. SOLOVKIN, Z. N. ZVETKOVA, Zh. Neorg. Khim., 12 (1967) 626.

    CAS  Google Scholar 

  11. A. G. RYKOV, N. N. ANDREYCHUK, V. Y. VASILYEV, Radiokhimiya, 15 (1973) 347.

    CAS  Google Scholar 

  12. A. G. RYKOV, N. B. BLOKHIN, V. Y. VASILYEV, Radiokhimiya, 15 (1973) 341.

    CAS  Google Scholar 

  13. G. A. SIMAKIN, A. G. RYKOV, P. F. BAKLANOVA, Radiokhimiya, 16 (1974) 512.

    Google Scholar 

  14. S. W. BAGAWDE, V. V. RAMAKRISHNA, S. K. PATIL, J. Inorg. Nucl. Chem., 38 (1976) 1339.

    Article  CAS  Google Scholar 

  15. I. M. BATYAYEV, V. V. PALCHEVSKIY, M. S. ZAKHARYEVSKIY, E. F. STRIZHEV, Fizicheskiye svoystva rastvorov, Leningrad University, 1964, p. 148.

  16. I. A. LEBEDYEV, B. F. MYASOYEDOV, V. Y. FRENKEL, Zh. Neorg. Khim., 18 (1973) 3224.

    Google Scholar 

  17. A. G. RYKOV, V. Y. VASILYEV, Radiokhimiya, 12 (1970) 717.

    CAS  Google Scholar 

  18. R. D. BAYBARZ, J. R. STOKELY, J. R. PETERSON, J. Inorg. Nucl. Chem., 34 (1972) 739.

    Article  CAS  Google Scholar 

  19. Elektromigratsionny metod v fizicheskih i radiokhimicheskih issledovaniyah, V. P. SHVEDOV, Ed. Atomizdat, Moscow, 1971, p. 78.

    Google Scholar 

  20. F. CLANET, J. CLARENCE, M. VERRE, J. Chromatog., 13 (1964) 440.

    Article  CAS  Google Scholar 

  21. J. CELEDA, J. HOLUB, T. SMIROUS, Coll. Czech. Chem. Commun., 34 (1974) 3544.

    Google Scholar 

  22. A. V. STEPANOV, T. P. MAKAROVA, S. G. GRITCHENKO, J. Radioanal Chem., 21 (1974) 411.

    Article  CAS  Google Scholar 

  23. A. V. STEPANOV, Thesis, Khlopin Radium Inst., Leningrad, 1974, p. 17.

  24. A. V. STEPANOV, T. P. MAKAROVA, Radiokhimiya, 9 (1967) 58.

    CAS  Google Scholar 

  25. A. G. RYKOV, N. B. BLOKHIN, Radiokhimiya, 13 (1971) 843.

    CAS  Google Scholar 

  26. I. A. LEBEDEV, S. V. PIROZHKOV, G. N. YAKOVLEV, Radiokhimiya, 2 (1960) 549.

    CAS  Google Scholar 

  27. A. V. STEPANOV, Zh. Neorg. Khim., 18 (1973) 371.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Radium Institute, Leningrad, USSR

    T. P. Makarova & A. M. Fridkin

  2. Institute of Atomic Energy, Moscow, USSR

    V. N. Kosyakov

  3. Institute of Atomic Reactors, Dimitrovgrad, USSR

    E. A. Yerin

Authors
  1. T. P. Makarova
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  2. A. M. Fridkin
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  3. V. N. Kosyakov
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  4. E. A. Yerin
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Makarova, T.P., Fridkin, A.M., Kosyakov, V.N. et al. Electromigration of Bk(IV) and some other tetravalent cations in nitric acid solutions. J. Radioanal. Chem. 53, 17–24 (1979). https://doi.org/10.1007/BF02517902

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  • DOI: https://doi.org/10.1007/BF02517902

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