Abstract
The extraction of Y, La, Ce(III), Gd, Th, Fe(III), Co(II), Cu, Zn, Cd, Hg, In and Tl (I=0.1;T=20±2°C) with N-benzoyl-N-phenylhydroxylamine (N-BPHA) in chloroform has been studied in order to determine the composition, and the extraction and two-phase stability constants of the extracted chelates. The dissociation constant of N-BPHA in aqueous solution has also been determined.
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References
S. J. Lyle, A. D. Shendrikar,Radiochim. Acta, 3 (1964) 90.
S. J. Lyle, A. D. Shendrikar,Talanta, 12 (1965) 573.
S. J. Lyle, A. D. Shendrikar,Anal. Chim. Acta, 32 (1965) 575.
S. J. Lyle, A. D. Shendrikar,Anal. Chim. Acta, 36 (1966) 286.
S. J. Lyle, A. D. Shendrikar,Talanta, 13 (1966) 140.
G. K. Schweitzer, M. M. Anderson,Anal. Chim. Acta, 41 (1968) 23.
A. D. Shendrikar,Talanta, 16 (1969) 51.
D. Dyrssen,Acta Chem. Scand., 10 (1956) 353.
G. K. Schweitzer, M. M. Anderson,J. Inorg. Nucl. Chem., 30 (1968) 1051.
S. A. Hamid, I. P. Alimarin, I. V. Puzdrenkova,Vestnik Moskov. Univ., Ser. Khim., 20 (1965) No. 3, 71.
J. Růžička, J. Starý,Talanta, 14 (1968) 909.
J. Starý, The Solvent Extraction of Metal Chelates, Pergamon Press, Oxford, 1964.
G. Iwantscheff, Das Dithizon und seine Anwendung in der Mikro- und Spurenanalyse, Verlag Chemie, Weinheim, 1958.
J. Růžička, J. Starý, Substoichiometry in Radiochemical Analysis, Pergamon Press, Oxford, 1968.
A. Albert, E. Sergeant, Konstanty ionizacii kislot i osnovanii, Khimiya, Moscow, 1964.
N. K. Dutt, T. Seshadei,Bull. Chem. Soc. Japan, 40 (1967) 2280.
J. Bjerrum, G. Schwarzenbach, L. G. Sillén, Stability Constants of Metal-ion Complexes with Solubility Products of Inorganic Substances, Part II, Inorganic Ligands, Chem. Soc., London, 1958.
A. Riedel,J. Radioanal. Chem., 6 (1970) 75.
K. A. Kraus, R. W. Holmberg,J. Phys. Chem., 58 (1954) 325.
I. G. Perkov, N. P. Komar, V. V. Melnik,Zh. Analit. Khim., 22 (1967) 640.
I. G. Perkov, N. P. Komar,Zh. Analit. Khim., 22 (1967) 653.
J. Rydberg,Acta Chem. Scand., 4 (1950) 1503.
G. K. Schweitzer, L. H. Howe,Anal. Chim. Acta, 37 (1967) 316.
G. A. Brydon, D. E. Ryan,Anal. Chim. Acta, 35 (1966) 190.
G. K. Schweitzer, G. R. Coe,Anal. Chim. Acta, 24 (1961) 311.
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Riedel, A. Systematic study of the extraction of metals using N-benzoyl-N-phenylhydroxylamine. J. Radioanal. Chem. 13, 125–134 (1973). https://doi.org/10.1007/BF02514115
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DOI: https://doi.org/10.1007/BF02514115