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Systematic study of the extraction of metals using N-benzoyl-N-phenylhydroxylamine

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Abstract

The extraction of Y, La, Ce(III), Gd, Th, Fe(III), Co(II), Cu, Zn, Cd, Hg, In and Tl (I=0.1;T=20±2°C) with N-benzoyl-N-phenylhydroxylamine (N-BPHA) in chloroform has been studied in order to determine the composition, and the extraction and two-phase stability constants of the extracted chelates. The dissociation constant of N-BPHA in aqueous solution has also been determined.

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References

  1. S. J. Lyle, A. D. Shendrikar,Radiochim. Acta, 3 (1964) 90.

    CAS  Google Scholar 

  2. S. J. Lyle, A. D. Shendrikar,Talanta, 12 (1965) 573.

    Article  CAS  Google Scholar 

  3. S. J. Lyle, A. D. Shendrikar,Anal. Chim. Acta, 32 (1965) 575.

    Article  CAS  Google Scholar 

  4. S. J. Lyle, A. D. Shendrikar,Anal. Chim. Acta, 36 (1966) 286.

    Article  CAS  Google Scholar 

  5. S. J. Lyle, A. D. Shendrikar,Talanta, 13 (1966) 140.

    Article  CAS  Google Scholar 

  6. G. K. Schweitzer, M. M. Anderson,Anal. Chim. Acta, 41 (1968) 23.

    Article  CAS  Google Scholar 

  7. A. D. Shendrikar,Talanta, 16 (1969) 51.

    Article  CAS  Google Scholar 

  8. D. Dyrssen,Acta Chem. Scand., 10 (1956) 353.

    CAS  Google Scholar 

  9. G. K. Schweitzer, M. M. Anderson,J. Inorg. Nucl. Chem., 30 (1968) 1051.

    Article  CAS  Google Scholar 

  10. S. A. Hamid, I. P. Alimarin, I. V. Puzdrenkova,Vestnik Moskov. Univ., Ser. Khim., 20 (1965) No. 3, 71.

    CAS  Google Scholar 

  11. J. Růžička, J. Starý,Talanta, 14 (1968) 909.

    Google Scholar 

  12. J. Starý, The Solvent Extraction of Metal Chelates, Pergamon Press, Oxford, 1964.

    Google Scholar 

  13. G. Iwantscheff, Das Dithizon und seine Anwendung in der Mikro- und Spurenanalyse, Verlag Chemie, Weinheim, 1958.

    Google Scholar 

  14. J. Růžička, J. Starý, Substoichiometry in Radiochemical Analysis, Pergamon Press, Oxford, 1968.

    Google Scholar 

  15. A. Albert, E. Sergeant, Konstanty ionizacii kislot i osnovanii, Khimiya, Moscow, 1964.

    Google Scholar 

  16. N. K. Dutt, T. Seshadei,Bull. Chem. Soc. Japan, 40 (1967) 2280.

    Article  CAS  Google Scholar 

  17. J. Bjerrum, G. Schwarzenbach, L. G. Sillén, Stability Constants of Metal-ion Complexes with Solubility Products of Inorganic Substances, Part II, Inorganic Ligands, Chem. Soc., London, 1958.

  18. A. Riedel,J. Radioanal. Chem., 6 (1970) 75.

    CAS  Google Scholar 

  19. K. A. Kraus, R. W. Holmberg,J. Phys. Chem., 58 (1954) 325.

    Article  CAS  Google Scholar 

  20. I. G. Perkov, N. P. Komar, V. V. Melnik,Zh. Analit. Khim., 22 (1967) 640.

    Google Scholar 

  21. I. G. Perkov, N. P. Komar,Zh. Analit. Khim., 22 (1967) 653.

    CAS  Google Scholar 

  22. J. Rydberg,Acta Chem. Scand., 4 (1950) 1503.

    Article  CAS  Google Scholar 

  23. G. K. Schweitzer, L. H. Howe,Anal. Chim. Acta, 37 (1967) 316.

    Article  CAS  Google Scholar 

  24. G. A. Brydon, D. E. Ryan,Anal. Chim. Acta, 35 (1966) 190.

    Article  CAS  Google Scholar 

  25. G. K. Schweitzer, G. R. Coe,Anal. Chim. Acta, 24 (1961) 311.

    Article  CAS  Google Scholar 

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Riedel, A. Systematic study of the extraction of metals using N-benzoyl-N-phenylhydroxylamine. J. Radioanal. Chem. 13, 125–134 (1973). https://doi.org/10.1007/BF02514115

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