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Mechanism of the primary stages of decomposition of aliphatic nitro- and fluoronitronitramines

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The primary stage of the decomposition of compounds RN(NO2)CH2C(NO2)2X is the homolytic cleavage of the C−NO2 bond, at X=NO2 and N−NO2 bond at X=F. The inductive effect of substituents decreases the dissociation energies of the C−N and N−N bonds by 1–2 kcal mol−1. Kinetic effects caused by the spatial interaction of groups and by stepwise decomposition of polyfunctional compounds are described.

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Authors and Affiliations

  1. Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation

    B. L. Korsounskii, V. G. Matveev, L. D. Nazina & G. M. Nazin

Authors
  1. B. L. Korsounskii
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  2. V. G. Matveev
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  3. L. D. Nazina
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  4. G. M. Nazin
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 259–264, February, 1998.

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Korsounskii, B.L., Matveev, V.G., Nazina, L.D. et al. Mechanism of the primary stages of decomposition of aliphatic nitro- and fluoronitronitramines. Russ Chem Bull 47, 253–258 (1998). https://doi.org/10.1007/BF02498944

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  • DOI: https://doi.org/10.1007/BF02498944

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