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Isomerism of copper(II) coordination compounds with hydroxamic acids

  • Physical Chemistry
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Abstract

The structure of CuII complexes with hydroxamic acids Cu[R1N(O)−(O)CR2]2, where R1=Ph, R2=Me; R1=Me, R2=Ph, was studied by ESR spectroscopy. In toluene solutions and low-temperature glasses, the complexes exist as two forms, which were identified ascis-andtrans-isomers. The proportions of the isomers were determined.

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References

  1. A. Werner,Novye vozzreniya v oblasti neorganicheskoi khimii [New Views in the Field of Inorganic Chemistry], ONTI, Leningrad, 1936, 506 pp. (Russ. Transl.).

    Google Scholar 

  2. A. A. Grinberg,Vvedenie v khimiyu kompleksnykh soedinenii [Introduction the Chemistry of Complex Compounds], Khimiya, Leningrad; 1966, 632 pp. (in Russian).

    Google Scholar 

  3. K. Abu-Dari, J. D. Ekstrand, D. P. Freyberg, and K. N. Raymond,Inorg. Chem., 1979,18, 108.

    Article  CAS  Google Scholar 

  4. J. Becher, D. J. Brockway, K. S. Murray, P. J. Newman, and H. Toflund,Inorg. Chem., 1982,21, 1791.

    Article  CAS  Google Scholar 

  5. G. M. Larin, A. V. Rotov, and V. I. Dzyuba,Dokl. Akad. Nauk, 1995,344, 779 [Dokl. Chem., 1995 (Engl. Transl.)].

    CAS  Google Scholar 

  6. V. I. Dzyuba, T. V. Ternovaya, N. A. Kostromina, and A. I. Ksaverov,Ukr. Khim. Zh. [Ukrainian Chem. J.], 1986,52, 453 (in Russian).

    CAS  Google Scholar 

  7. G. M. Larin, G. A. Zvereva, V. V. Minin, and Yu. V. Rakitin,Zh. Neorgan. Khim., 1988,33, 2011 [J. Inorg. Chem. USSR, 1988,33 (Engl. Transl.)].

    CAS  Google Scholar 

  8. Yu. V. Rakitin, G. M. Larin, and V. V. Minin,Interpretatsiya spektrov EPR koordinatsionnykh soedinenii [Interpretation of the ESR Spectra of Coordination Compounds], Nauka, Moscow, 1993, 399 pp. (in Russian).

    Google Scholar 

  9. G. M. Larin,Teor. Eksp. Khim., 1968,4, 244 [Theor. Exp. Chem., 1968,4 (engl. Transl.)].

    CAS  Google Scholar 

  10. G. M. Larin,Koord. Khim., 1993,19, 91 [Russ. Coord. chem., 1993,19 (Engl. Transl.)].

    CAS  Google Scholar 

  11. V. A. Kogan, V. V. Zelentsov, G. M. Larin, and V. V. Lukov,Kompleksy perekhodnykh metallov s gidrazonami [Transition Metal Complexes with Hydrazones], Nauka, Moscow, 1990, 112 pp. (in Russian).

    Google Scholar 

  12. H. A. Kuska and M. T. Rogers,J. Phys. Chem., 1967,71, 109.

    CAS  Google Scholar 

  13. G. M. Larin and M. E. Dyatkina,Izv. Akad. Nauk SSSR, Ser. Khim., 1972, 1413 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1972,21, 1364 (Engl. Transl.)].

  14. O. P. Charkin, G. V. Bobykina, and M. E. Dyatkina, inStroenie molekul i kvantovaya khimiya [Molecular Structure and Quantum Chemistry], Naukova dumka, Kiev, 1970, p. 155 (in Russian).

    Google Scholar 

  15. O. P. Charkin and M. E. Dyatkina, inStroenie molekul i kvantovaya khimiya [Molecular Structure and Quantum Chemistry], Naukova dumka, Kiev, 1970, p. 163 (in Russian).

    Google Scholar 

  16. W. L. Smith and K. N. Raymond,J. Am. Chem. Soc., 1981,103, 3341.

    Article  CAS  Google Scholar 

  17. D. A. Brown, D. McKeith, and W. K. Glass,Inorg. Chim. Acta, 1979,35, 57.

    Article  CAS  Google Scholar 

  18. G. M. Larin, Sc. (Chem.) Thesis, Institute of General and Inorganic Chemistry, Moscow, 1974, 318 pp. (in Russian).

  19. Yu. N. Kukushkin,Khimiya koordinatsionnykh soedinenii [Chemistry of Coordination Compounds], Vysshaya shkola, Moscow, 1985, 455 pp. (in Russian).

    Google Scholar 

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 726–729, April, 1999.

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Larin, G.M., Rotov, A.V. & Dzyuba, V.I. Isomerism of copper(II) coordination compounds with hydroxamic acids. Russ Chem Bull 48, 722–725 (1999). https://doi.org/10.1007/BF02496255

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  • DOI: https://doi.org/10.1007/BF02496255

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