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Reactions of 3-amino-1-phenyl- and 3-amino-1-(thien-2-yl)-4,4,4-trifluorobut-2-en-1-ones with 1,2-diaminopropane and 1,2-diamino-3,3,3-trifluoropropane

  • Organic Chemistry
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Abstract

The reactions of 3-amino-1-phenyl-and 3-amino-1-(thien-2-yl)-4,4,4-trifluorobut-2-en-1-ones with 1,2-diaminopropane under kinetically controlled conditions afford mixtures ofcis andtrans isomers of 2-aroylmethyl-4-methyl-2-trifluoromethylimidazolidines. Analogous reactions with 1,2-diamino-3,3,3-trifluoropropane yieldcis-2-aroylmethyl-2,4-bis(trifluoro-methyl)imidazolidines.

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Authors and Affiliations

  1. A. M. Gorky Ural State University, 51 prosp. Lenina, 620083, Ekaterinburg, Russian Federation

    V. Ya. Sosnovskikh, V. A. Kutsenko, A. Ya. Aizikovich & V. Yu. Korotaev

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  1. V. Ya. Sosnovskikh
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  2. V. A. Kutsenko
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  3. A. Ya. Aizikovich
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  4. V. Yu. Korotaev
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2135–2139, November, 1999.

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Sosnovskikh, V.Y., Kutsenko, V.A., Aizikovich, A.Y. et al. Reactions of 3-amino-1-phenyl- and 3-amino-1-(thien-2-yl)-4,4,4-trifluorobut-2-en-1-ones with 1,2-diaminopropane and 1,2-diamino-3,3,3-trifluoropropane. Russ Chem Bull 48, 2112–2116 (1999). https://doi.org/10.1007/BF02494858

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  • DOI: https://doi.org/10.1007/BF02494858

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