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Interaction of levoglucosenone with malononitrile

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Abstract

Levoglucosenone reacts with malononitrile to form a product with a complex structure, which contains two levoglucosenone molecules and three malononitrile molecules. The conclusion about the structure of the product was based on the data of NMR, IR, and UV spectroscopy and mass spectrometry. The suggested reaction mechanism involves cascade cyclization.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    A. V. Samet, N. B. Chernysheva, A. M. Shestopalov & V. V. Semenov

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  1. A. V. Samet
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  2. N. B. Chernysheva
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  3. A. M. Shestopalov
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  4. V. V. Semenov
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 208–210, January, 1999.

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Samet, A.V., Chernysheva, N.B., Shestopalov, A.M. et al. Interaction of levoglucosenone with malononitrile. Russ Chem Bull 48, 210–212 (1999). https://doi.org/10.1007/BF02494434

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  • DOI: https://doi.org/10.1007/BF02494434

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