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Influence of chemical modification of polymeric resin on retention of polar compounds in solid-phase extraction

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Summary

Three polymeric adsorbents, two of which had been chemically modified with different hydrophilic functional moieties and the third, which was the corresponding unmodified polystyrene-divinylbenzene (PSDVB) resin, were compared for solid-phase extraction (SPE) of several polar pesticides and phenolic compounds from water samples. The SPE system was online coupled to a liquid chromatograph with UV detector.

Chemical modification of the PS-DVB resin with either 2-carboxy-3/4-nitrobenzoyl or 2,4-dicarboxybenzoyl, improved the efficiency of the SPE process by increasing polar interactions with the analytes. The adsorbent with the nitro group gave higher recoveries, mainly for the most polar analytes. This adsorbent enabled 100 mL river water to be preconcentrated to determine the target analytes in this matrix.

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References

  1. J. J. Sun, J. S. Fritz, J. Chromatogr.,522, 95 (1990).

    Article  CAS  Google Scholar 

  2. J. J. Sun, J. S. Fritz, J. Chromatogr.,590, 197 (1992).

    Article  CAS  Google Scholar 

  3. L. W. Schmidt, J. J. Sun, J. S. Fritz, D. F. Hagen, C. G. Markell, E. E. Wisted, J. Chromatogr.,641, 57 (1993).

    Article  CAS  Google Scholar 

  4. J. S. Fritz, P. J. Dumont, L. W. Schmidt, J. Chromatogr. A,691, 133 (1995).

    Article  CAS  Google Scholar 

  5. N. Cardellicchio, S. Cavalli, V. Piangerelli, S. Giandomenico, P. Ragone, Fresenius J. Anal. Chem.,358, 749 (1997).

    Article  CAS  Google Scholar 

  6. M. W. Powell, J. Chromatogr. A,697, 101 (1995).

    Article  CAS  Google Scholar 

  7. N. Masqué, M. Galià, R. M. Marcé, F. Borrull, J. Chromatogr. A,771, 55 (1997).

    Article  Google Scholar 

  8. N. Masqué, M. Galià, R. M. Marcé, F. Borrull, Analyst,122, 425 (1997).

    Article  Google Scholar 

  9. N. Masqué, M. Galià, R. M. Marcé, F. Borrull, J. Chromatogr. A,803, 147 (1998).

    Article  Google Scholar 

  10. N. Masqué, E. Pocurull, R. M. Marcé, F. Borrull, Chromatographia,47, 176 (1998).

    Article  Google Scholar 

  11. N. Masqué, R. M. Marcé, F. Borrull, Chromatographia,48, 231 (1998).

    Article  Google Scholar 

  12. N. Masqué, M. Galià, R. M. Marcé, F. Borrull, J. High Resolut. Chromatogr., (submitted for publication).

  13. N. Masqué, R. M. Marcé, F. Borrull, J. Chromatogr. A,793, 257 (1998).

    Article  Google Scholar 

  14. P. J. Dumont, J. S. Fritz, J. Chromatogr. A,691, 123 (1995).

    Article  CAS  Google Scholar 

  15. D. Puig, D. Barceló, I. Silgoner, M. Grasserbauer, J. Mass Spectrom.,31, 1297 (1996).

    Article  CAS  Google Scholar 

  16. M. R. Buchmeiser, N. Atzl, G. K. Bonn, J. Am. Chem. Soc.,119, 9166 (1997).

    Article  CAS  Google Scholar 

  17. D. L. Ambrose, J. S. Fritz, M. R. Buchmeiser, N. Atzl, G. K. Bonn, J. Chromatogr. A,786, 259 (1997).

    Article  CAS  Google Scholar 

  18. E. Pocurull, R. M. Marcé, F. Borrull, Chromatographia,41, 521 (1995).

    Article  CAS  Google Scholar 

  19. G. L. Long, J. D. Winefordner, Anal. Chem.,55, 712A (1983).

    CAS  Google Scholar 

  20. R. Boqué, F. X. Rius, J. Chem. Educ.,70, 230 (1993).

    Article  Google Scholar 

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Authors and Affiliations

  1. Departament de Química Analitica i Química Orgànica, Universitat Rovira i Virgili, Imperial Tarraco, 1, 43005, Tarragona, Spain

    N. Masqué, M. Galiá, R. M. Marcé & F. Borrull

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  1. N. Masqué
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  2. M. Galiá
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  3. R. M. Marcé
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  4. F. Borrull
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Masqué, N., Galiá, M., Marcé, R.M. et al. Influence of chemical modification of polymeric resin on retention of polar compounds in solid-phase extraction. Chromatographia 50, 21–26 (1999). https://doi.org/10.1007/BF02493612

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  • DOI: https://doi.org/10.1007/BF02493612

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