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Retention behavior of monosaccharides and disaccharides on titania

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  • Column Liquid Chromatography
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Summary

The ability of titania to recognize the position of hydroxyl groups was previously found to result from the formation of a chelate ring between a titanium ion and the two oxygen atoms of the hydroxyl group and carboxylate anion of 2-hydroxycarboxylic acids. We investigated how titania could recognize the position of hydroxyl group of monosaccharides and disaccharides. The retention behavior of monosaccharides and disaccharides on titania was found to be characteristic. Thus, sucrose was eluted much faster than the other sugars, whereas D-ribose, D-fructose and L-sorbose were most strongly retained on titania of all of the sugars tested. It is apparent that the sugars strongly retained on titania have an axial hydroxyl group or neighboring hydroxyl groups of the same conformation.

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Authors and Affiliations

  1. Department of Chemistry and Biotechnology, Faculty of Engineering, Yamanashi University, 3-11 Takeda-4, 400-8511, Kofu, Japan

    K. Tani, M. Kitada, M. Tachibana, H. Koizumi & T. Kiba

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  1. K. Tani
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  2. M. Kitada
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  3. M. Tachibana
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  4. H. Koizumi
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  5. T. Kiba
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Tani, K., Kitada, M., Tachibana, M. et al. Retention behavior of monosaccharides and disaccharides on titania. Chromatographia 57, 409–412 (2003). https://doi.org/10.1007/BF02492416

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  • DOI: https://doi.org/10.1007/BF02492416

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