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Iron complexes in zeolites as a new model of methane monooxygenase

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Abstract

Iron complexes in the ZSM-5 zeolite matrix (α-centers) are shown to perform single-turnover cycles of methane oxidation to methanol at room temperature when nitrous oxide is used as a source of oxygen. The origin of carbon and oxygen in the product methanol was traced using13C and18O isotopes. Probable structure of α-sites as well as mechanistic features of the reaction allow to consider this system as a first successful model of methane monooxygenase.

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Authors and Affiliations

  1. Federal Scientific Center, Boreskov Institute of Catalysis, 630090, Novosibirsk, Russia

    G. I. Panov, V. I. Sobolev, K. A. Dubkov & V. N. Parmon

  2. Institute of Chemical Physics in Chernogolovka, Moscow Region, 142432, Chernogolovka, Russia

    N. S. Ovanesyan, A. E. Shilov & A. A. Shteinman

Authors
  1. G. I. Panov
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  2. V. I. Sobolev
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  3. K. A. Dubkov
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  4. V. N. Parmon
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  5. N. S. Ovanesyan
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  6. A. E. Shilov
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  7. A. A. Shteinman
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Panov, G.I., Sobolev, V.I., Dubkov, K.A. et al. Iron complexes in zeolites as a new model of methane monooxygenase. React Kinet Catal Lett 61, 251–258 (1997). https://doi.org/10.1007/BF02478380

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  • DOI: https://doi.org/10.1007/BF02478380

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