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Rhodium amino complexes [Rh(COD)(Amine)2]PF6 immobilized on poly(4-vinylpyridine) as catalysts in the water gas shift reaction

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Abstract

Catalysts for the water gas shift reaction prepared from Rh(COD)(amine)2 PF6 (COD=1,5-cyclooctadiene, amine=4-picoline, 3-picoline, 2-picoline, pyridine, 3,5-lutidine or 2,6-lutidine) immobilized on poly(4-vinylpyridine) in contact with 80% aqueoux 2-ethoxyethanol for 1×10−4 mol Rh/0.5 g of polymer, P(CO)=0.9 atm at 100 °C, are described. The role of the coordinated amine effect on the catalytic activity was investigated.

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References

  1. D.S. Newsome:Catal. Rev. Sci. Eng.,21, 275 (1980).

    CAS  Google Scholar 

  2. P.C. Ford, A. Rokicki:Adv. Organometall. Chem.,28, 139 (1988).

    Article  CAS  Google Scholar 

  3. A.J. Pardey, P.C. Ford:J. Mol. Catal.,53, 247 (1989).

    Article  CAS  Google Scholar 

  4. G. Fachinetti, T. Funaioli, L. Lecci, F. Marchetti:Inorg. Chem.,35, 7217 (1996).

    Article  CAS  Google Scholar 

  5. M. Fernández, M. Meza, M. Mediavilla, C. Longo, S.A. Moya, F. López, P. Baricelli, A.J. Pardey:Anal. Quím. Int. Ed.,94, 127 (1998).

    Google Scholar 

  6. M. Mediavilla, D. Pineda, F. López, D. Moronta, C. Longo, S.A. Moya, P. Baricelli, A.J. Pardey:Polyhedron,17, 1621 (1998).

    Article  CAS  Google Scholar 

  7. K. Kaneda, T. Takemoto, K. Kitaoka, T.T. Imanaka:Organometallics,10, 846 (1991).

    Article  CAS  Google Scholar 

  8. M. Mdleleni, R.G. Rinker, P.C. Ford:J. Mol. Catal.,89, 283 (1994).

    Article  CAS  Google Scholar 

  9. S.A. Moya, R. Sariego, P. Aguirre, R. Sartori, P. Dixneuf:Bull. Soc. Chim. Belg.,104, 19 (1995).

    Article  CAS  Google Scholar 

  10. M. Ferández, M. Mediavilla, M. Canestrari, S.A. Moya, C. Longo, P. Baricelli, A.J. Pardey:Rev. Soc. Venez. Catátl.,11, 37 (1997).

    Google Scholar 

  11. M. Haukka, T. Venalainen, M. Kallinene, T.A. Pakkanene:J. Mol. Catal. A,136, 127 (1998).

    Article  CAS  Google Scholar 

  12. R.P. Pant, S.B. Halligudi, R.R. Shukla, D.K. Suri, R.V. Metha:React. Kinet. Catal. Lett.,64, 109 (1998).

    CAS  Google Scholar 

  13. E.A. Bekturov, S.E. Kudaibergerov:Catalysis by Polymers, Huthig & Wepf Zug, Deidelberg, Oxford, CT/USA 1996.

    Google Scholar 

  14. B. Denise, G. Pannetier:J. Organometall. Chem.,63, 423 (1973).

    Article  CAS  Google Scholar 

  15. J.M. Prausnitz:Molecular Thermodynamics of Fluid-Phase Equilibria, ch. 8. Prentice-Hall, Englewood Cliffs, NJ 1969.

    Google Scholar 

  16. K. Schofield:Heter-Aromatic Nitrogen Compounds, p. 146–148. Plenum Press, New York 1967.

    Google Scholar 

  17. A.J. Pardey, M. Fernández, C. Longo, P. Baricelli, E. Lujano, J. Guerrero, S.A. Moya:React. Kinet. Catal. Lett.,65, 315 (1998).

    CAS  Google Scholar 

  18. J. Skupinskan, G. Smólka:React. Kinet. Catal. Lett.,63, 313 (1998).

    Google Scholar 

  19. M.M. Mdleleni, R.G. Rinker, P.C. Ford:Inorg. Chim. Acta,270, 352 (1998).

    Article  Google Scholar 

  20. V.D. Mattera, Jr., P.J. Squattrito, W.M. Risen:Inorg. Chem.,23, 3597 (1984).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Facultad de Ciencias, Escuela de Química, Universidad Central de Venezuela, Caracas, Venezuela

    A. J. Pardey, M. Fernández & M. Canestrari

  2. Centro de Investigaciones Químicas, Facultad de Ingeniería, Universidad de Carabobo, Valencia, Venezuela

    P. Baricelli & E. Lujano

  3. Facultad de Farmacia, Universidad Central de Venezuela, Caracas, Venezuela

    C. Longo

  4. Departmento of Química Aplicada, Facultad de Química y Biología, Universidad de Santiago de Chile, Santiago de Chile, Chile

    R. Sartori & S. A. Moya

Authors
  1. A. J. Pardey
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  2. M. Fernández
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  3. M. Canestrari
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  4. P. Baricelli
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  5. E. Lujano
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  6. C. Longo
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  7. R. Sartori
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  8. S. A. Moya
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Pardey, A.J., Fernández, M., Canestrari, M. et al. Rhodium amino complexes [Rh(COD)(Amine)2]PF6 immobilized on poly(4-vinylpyridine) as catalysts in the water gas shift reaction. React Kinet Catal Lett 67, 325–331 (1999). https://doi.org/10.1007/BF02475779

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  • DOI: https://doi.org/10.1007/BF02475779

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